微波-尿素协同处理对压缩密实化木材尺寸稳定性及抗弯性能的影响OA
Effect of Microwave-Urea Synergistic Treatment on the Dimensional Stability and Bending Properties of Compresseion-Densified Wood
以毛泡桐(Paulownia tomentosa)木材为研究对象,首先采用微波预处理,然后经尿素溶液(质量分数为30%)软化后热压制备压缩密实化木材(简称为压缩木材),主要探究不同微波预处理时间对压缩木材尺寸稳定性及抗弯性能的影响.结果表明,当热压温度为170℃时,随着微波预处理时间的延长,木材增重率和密度均显著增加(P<0.01),与未处理材相比,分别提高了7.42%~136.13%和10.71%~39.29%,剖面密度分布趋于均匀.微波-尿素协同处理对压缩木材的尺寸稳定性具有显著作用(P<0.01),当微波预处理时间为10~50 s时,压缩木材的吸水回复率、湿胀率较对照组(仅热压处理的木材)分别降低44.95%~60.81%、31.08%~50.00%.压缩木材的抗弯强度和弹性模量均随微波预处理时间的延长呈先增加后降低的趋势,在微波预处理时间为40 s(临界时间)时达到最大,较未处理材分别提升了45.45%和37.62%(P<0.05).微波-尿素协同处理发挥了二者的作用:微波处理引发木材内部膨化,使尿素溶液充分渗透到木材细胞壁中,在热压过程中尿素发挥软化作用,并与细胞壁发生交联反应,从而有效降低压缩木材的变形回复率并提升其抗弯性能.研究结果为高稳定性压缩木材的制备与应用提供理论基础.
This study investigated the effect of microwave pretreatment time on the dimensional stability and bending properties of compression-densified wood(referred as densified wood).Paulownia tomentosa was pretreatment by microwave,then softened by urea solution(mass fraction of 30%),and followed by hot-pressing to produce densified wood.The results showed that when the hot pressing temperature was 170℃,the weight percent gain and density of densified wood significantly increased(P<0.01)with the extension of microwave pretreatment time.Compared with untreated wood,these two indexes were increased by 7.42%~136.13%and 10.71%~39.29%,respectively,with the density profile becoming relatively uniform.Microwave urea synergistic treatment significantly improved the dimensional stability of densified wood(P<0.01).When the microwave pretreatment time was 10~50 s,the set recovery rate and swelling efficiency were decreased by 44.95%~60.81%and 31.08%~50.00%,respectively,compared with control group(treated only by hot-pressing).Both bending strength and modulus of elasticity of densified wood were initially increased and then decreased with the extension of microwave pretreatment time,reaching their maximum at a microwave pretreatment time of 40 seconds(critical time),which increased by 45.45%and 37.62%,respectively,compared with untreated wood(P<0.05).The combined effect of microwave-urea was demonstrated,i.e.,microwave treatment induced puffing within the wood,allowing the urea solution to fully penetrate the wood cell walls.During hot-pressing,urea softened and crosslinked with the cell walls,effectively reducing the set recovery rate of densified wood and improving its bending performance.The research results could provide a theoretical basis for the preparation and application of high-performance densified wood.
李思仪;王志闯;王婷欢;余晖;王孜;何正斌;王振宇;伊松林
林木资源高效生产全国重点实验室,木材科学与工程北京市重点实验室,木质材料科学与应用教育部重点实验室,北京林业大学材料科学与技术学院,北京 100083林木资源高效生产全国重点实验室,木材科学与工程北京市重点实验室,木质材料科学与应用教育部重点实验室,北京林业大学材料科学与技术学院,北京 100083林木资源高效生产全国重点实验室,木材科学与工程北京市重点实验室,木质材料科学与应用教育部重点实验室,北京林业大学材料科学与技术学院,北京 100083林木资源高效生产全国重点实验室,木材科学与工程北京市重点实验室,木质材料科学与应用教育部重点实验室,北京林业大学材料科学与技术学院,北京 100083林木资源高效生产全国重点实验室,木材科学与工程北京市重点实验室,木质材料科学与应用教育部重点实验室,北京林业大学材料科学与技术学院,北京 100083林木资源高效生产全国重点实验室,木材科学与工程北京市重点实验室,木质材料科学与应用教育部重点实验室,北京林业大学材料科学与技术学院,北京 100083林木资源高效生产全国重点实验室,木材科学与工程北京市重点实验室,木质材料科学与应用教育部重点实验室,北京林业大学材料科学与技术学院,北京 100083林木资源高效生产全国重点实验室,木材科学与工程北京市重点实验室,木质材料科学与应用教育部重点实验室,北京林业大学材料科学与技术学院,北京 100083
农业科技
微波预处理尿素压缩密实化木材细胞壁尺寸稳定性抗弯性能
microwave pretreatmentureacompression-densified woodcell walldimensional stabilitybending property
《木材科学与技术》 2026 (2)
49-57,9
"十四五"国家重点研发计划课题"高能微波膨化木质重组材料制造关键技术"(2023YFD2201402).
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