碱-硫酸根激发淤泥流态固化土强度与微观结构分析OA
Strength and microstructural properties of alkali-sulfate activated sludge fluid-solidified soil
相较于传统水泥固化技术,碱-硫酸根复合激发固化技术具有低能耗与资源循环利用率高等优势,但其在淤泥固化领域的实际效果与环境适应性研究仍有待深入.本研究采用碱-硫酸根复合激发技术,以矿粉为碱激发材料、脱硫石膏为硫酸根来源,制备淤泥流态固化土.通过无侧限抗压、直剪、劈裂及干湿循环试验,结合扫描电镜(SEM)和X射线衍射(XRD)分析,系统探究了该固化土的宏观力学性能、微观结构演化及其固化机理.结果表明:复合流态固化土在无侧限抗压强度、抗剪强度、抗干湿循环性能和间接抗拉强度等关键指标上均显著优于水泥流态固化土;其孔隙率、平均孔隙面积和概率熵均低于水泥流态固化土,且面积概率分布指数更高,表明其孔隙结构更加致密、均匀;复合激发技术通过碱性环境与硫酸根离子的协同作用,加速了氢氧化钙(CH)向水化硅酸钙(C-S-H)和水化铝酸钙(C-A-H)的转化,形成了致密的胶结网络,提升了固化土的密实度与力学强度.本研究可为碱-硫酸根复合激发固化技术在淤泥固化领域的工程应用提供理论参考和实践依据.
Compared to traditional cement solidification technology,alkali-sulfate composite activation solidification offers advantages such as low energy consumption and high resource recycling rates.However,its practical solidification effects and environmental adaptability in sludge solidification applications require further investigation.In this study,alkali-sulfate composite activation technology was employed to prepare sludge fluid-solidified soil,using ground granulated blast furnace slag as the alkali-activated material and flue gas desulfurization gypsum as the sulfate source.Tests,including unconfined compressive strength,direct shear,splitting,and wet-dry cycles,were conducted.Additionally,scanning electron microscopy(SEM)and X-ray diffraction(XRD)analyses were performed to examine the macro-mechanical properties,microstructural evolution,and solidification mechanisms.The results show that composite fluid-solidified soil significantly outperforms cement-based fluid-solidified soil in key indicators such as compressive strength,shear strength,wet-dry cycle resistance,and splitting tensile strength.It also exhibits lower porosity,average pore area,and probability entropy,along with a higher area probability distribution index,indicating a denser and more uniform pore structure.The alkali-sulfate composite activation technology accelerates the conversion of calcium hydroxide(CH)to calcium silicate hydrate(C-S-H)and calcium aluminate hydrate(C-A-H)through the synergistic action of alkali and sulfate ions.This forms a dense cementation network,improving the soil's density and mechanical strength.This study provides both theoretical and practical insights for the application of alkali-sulfate composite activation solidification in sludge treatment.
张玲;叶虔江;周智游
湖南大学 土木工程学院,湖南 长沙 410082湖南大学 土木工程学院,湖南 长沙 410082湖南大学 土木工程学院,湖南 长沙 410082
建筑与水利
水泥固化土淤泥流态固化土碱-硫酸根复合激发宏观性能微观结构
cement-based solidified soilsludge fluid-solidified soilalkali-sulfate composite activationmac-roscopic performancemicrostructure
《湖南大学学报(自然科学版)》 2026 (5)
77-88,12
国家自然科学基金资助项目(52078205,52108317),National Natural Science Foundation of China(52078205,52108317)湖南省自然科学基金资助项目(2020JJ3013),Natural Science Foundation of Hunan Province(2020JJ3013)
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