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电场作用下含表面活性剂液滴界面输运及变形机理OA

Interface transport and deformation mechanism of surfactant-containing droplet under electric field

中文摘要英文摘要

结合ALE(arbitrary Lagrange-Euler)方法、多相流动控制方程、界面对流扩散方程、电场控制方程及表面活性剂界面吸附理论建立含表面活性剂液滴变形动力学模型,本文阐明了液滴变形过程中的电场、流场和表面活性剂界面浓度场分布演化规律,得到了表面活性剂吸附量和连续相黏度对液滴变形过程中表面活性剂界面不均匀分布的影响规律.在研究的稳态变形范围内,本文模型的数值计算结果与过往的实验结果及已有文献结果高度吻合,充分证明了所建模型的可靠性.结果表明:液滴内部在电场作用下形成4个对称的环流,促使表面活性剂从液滴腹部聚集到液滴两端;随着表面活性剂初始吸附比的增加(Г*>0.1),Marangoni应力逐渐占主导,表面活性剂发生反向输运;油相黏度主要影响变化过程中表面活性剂的运移时间和运移方向.本文研究结果为静电破乳、微流控、静电喷雾等复杂的工程电流体动力学研究提供了理论基础.

Combined with the ALE(arbitrary Lagrange-Euler)method,the governing equation of multiphase flow,the governing equation of electric field and the interface transport equation of surfactant,a dynamic model of surfactant-containing droplets under electric field was established,the evolution of the distribution of electric field,flow field and surfactant interfacial concentration field during droplet deformation was clarified,and the influence of surfactant adsorption capacity and continuous phase viscosity on the uneven distribution of surfactant interface during droplet deformation was obtained.Within the studied steady-state deformation regime,the simulation results predicted by the dynamic mesh method showed excellent agreement with experimental data,validating the accuracy of the proposed model.The results showed that four symmetrical circulations were formed inside the droplets under the action of electric field,which promoted the accumulation of surfactants from the belly of the droplets to both ends of the droplets.With the increase of the adsorption ratio of surfactant(Г*>0.1),Marangoni stress gradually dominated,and the surfactant was transported in the opposite direction.The viscosity of the oil phase mainly affected the migration time and direction of the surfactant during the change process.The results of this study could provide theoretical guidance for the study of complex engineering current fluid dynamics such as electrostatic dehydration,electrostatic spray,and microfluidics.

黄鑫;付亚晶;陆奕嘉;吴家桥;林宇昇;罗小明;张贺军;滕霖;江莉龙

福州大学化工学院,福建 福州 350108福州大学化工学院,福建 福州 350108福州大学化工学院,福建 福州 350108福州大学化工学院,福建 福州 350108福州大学化工学院,福建 福州 350108中国石油大学(华东)储运与建筑工程学院,山东 青岛 266580中海石油(中国)有限公司深圳分公司,广东 深圳 518000福州大学化工学院,福建 福州 350108福州大学化工学院,福建 福州 350108

能源科技

电场液滴变形表面活性剂界面输运Marangoni效应

electric fielddroplet deformationsurfactantsinterface transportMarangoni effect

《化工进展》 2026 (5)

2607-2618,12

国家自然科学基金青年科学基金(52204073)国家自然科学基金面上项目(22578066,52474089,22478080)福建省自然科学基金(2024J01284).

10.16085/j.issn.1000-6613.2025-0825

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