烟气基质下烤甜香韵天然香料与合成香料间香味相互作用研究OA
Aroma interactions between natural and synthetic flavorings with roasted sweet note in a cigarette smoke matrix
[目的]揭示烤甜香韵天然与合成香料在卷烟烟气基质下的香味阈值与相互作用规律.[方法]利用气相色谱-质谱联用(GC-MS)技术明确 4 种烤甜香韵天然香料中香气成分种类和含量,通过 S 曲线法测定烟气基质下4 种烤甜香韵天然香料和8 种烤甜香韵合成香料香味阈值,并结合 Feller 加和模型明确天然与合成香料香味的相互作用.[结果]4 种天然香料中均含有甲基环戊烯醇酮(MCP)、2,3-二氢-3,5 二羟基-6-甲基-4(H)-吡喃-4-酮(DDMP)、5-羟甲基糠醛(5-HMF)、葫芦巴内酯等烤甜香韵挥发性成分.4 种天然香料的香味阈值范围为8.146×10-2~5.420×10-1 ng/支,8 种合成香料在烟气中的香味阈值范围为 5.140×10-7~6.041 ng/支.枫槭浸膏/MCP、枫槭浸膏/DDMP、葫芦巴提取物/乙基葫芦巴内酯、烟草美拉德反应产物/MCP 4 种二元组合,以及枫槭浸膏/麦芽酚/乙基麦芽酚、红枣浸膏/麦芽酚/乙基麦芽酚 2 种三元组合的香味之间呈现和合作用,红枣浸膏/MCP 组合香味之间呈现掩盖作用,其他 21 种二元组合均呈现加和作用.[结论]明确了卷烟烟气基质下烤甜香韵天然与合成香料的香味阈值范围及其相互作用规律,可为卷烟精准调香提供参考与借鉴.
[Objective]This study aimed to reveal the aroma thresholds and interaction patterns of natural and synthetic flavorings with roasted sweet note in a cigarette smoke matrix.[Methods]Gas chromatography-mass spectrometry(GC-MS)was employed to identify the aroma components in four natural flavorings with roasted sweet note.The S-curve method was then used to determine the aroma thresholds of these four natural flavorings and eight synthetic flavorings in a cigarette smoke matrix,and Feller's additive model was applied to elucidate the interactions between the natural and synthetic flavorings.[Results]1)All four natural flavorings contained roasted sweet aroma components such as methyl cyclopentenolone(MCP),2,3-dihydro-3,5-dihydroxy-6-methyl-4(H)-pyran-4-one(DDMP),5-hydroxy methyl furfural(5-HMF)and sotolone.2)The aroma thresholds of the eight synthetic flavorings ranged from 5.140×10-7 to 6.041 ng/cigarette,while those of the four natural flavorings ranged from 8.146×10-2 to 5.420×10-1 ng/cigarette.3)Synergistic effects were observed in four binary combinations(maple extract/MCP,maple extract/DDMP,fenugreek extract/ethyl sotolone,and tobacco Maillard reaction product/MCP)and two ternary systems(maple extract/maltol/ethyl maltol and jujube extract/maltol/ethyl maltol).A masking effect was observed in the jujube extract/MCP binary combination,whereas additive interactions dominated the other 21 binary combinations.[Conclusion]This study elucidated the aroma threshold ranges and interaction patterns of natural and synthetic flavorings with roasted sweet note in a cigarette smoke matrix,providing a reference for precision flavoring of cigarettes.
万帅;刘前进;席高磊;陈彪;张洁;臧翔宇;芦昶彤;李耀光
河南中烟工业有限责任公司 技术中心,河南 郑州 450000河南中烟工业有限责任公司 技术中心,河南 郑州 450000河南中烟工业有限责任公司 技术中心,河南 郑州 450000河南中烟工业有限责任公司 技术中心,河南 郑州 450000河南中烟工业有限责任公司 技术中心,河南 郑州 450000河南中烟工业有限责任公司 技术中心,河南 郑州 450000河南中烟工业有限责任公司 技术中心,河南 郑州 450000河南中烟工业有限责任公司 技术中心,河南 郑州 450000
轻工纺织
烟气烤甜香韵天然香料合成香料香味阈值S曲线相互作用规律
cigarette smokeroasted sweet aromanatural flavoringssynthetic flavoringsaroma thresholdS-curve methodinteraction pattern
《轻工学报》 2026 (3)
88-97,10
河南中烟工业有限责任公司科技项目(AW2022011),河南省人才托举工程项目(2022HYTP020).
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