羧甲基化改性对麦麸膳食纤维特性的影响OA
Effect of carboxymethylation modification on the characteristics of wheat bran dietary fiber
[目的]改善麦麸膳食纤维(Wheat Bran Dietary Fiber,WBDF)的理化特性、功能特性及结构特征,提高其资源利用率.[方法]采用羧甲基化改性处理 WBDF,并对比分析其改性前后的理化特性、功能特性及结构特征.[结果]成功制备出取代度为0.16 的羧甲基化麦麸膳食纤维(Carboxymethylated Wheat Bran Dietary Fiber,CWBDF),其可溶性膳食纤维含量由改性前的 3.31%提高到 20.76%,持水力、持油力和膨胀力分别提升至改性前的1.81 倍、1.31 倍和1.30 倍,葡萄糖吸附能力最高提升至改性前的2.18 倍,胆固醇吸附能力显著提高且表现出良好的无 pH 依赖性,DPPH 和 ABTS+自由基清除率分别为改性前的 1.33 倍和 1.53 倍,总酚含量提高至改性前的1.74 倍,纤维素和半纤维素均发生降解,结晶区被破坏,形成疏松多孔结构,比表面积增大.[结论]羧甲基化改性能显著提高WBDF 中可溶性膳食纤维含量,是改善WBDF 物理结构并增强其加工和功能特性的有效途径.
[Objective]This study aimed to improve the physicochemical properties,functional properties,and structural characteristics of wheat bran dietary fiber(WBDF)and to enhance its resource utilization.[Methods]WBDF was subjected to carboxymethylation modification,and its physicochemical properties,functional properties,and structural characteristics pre-and post-modification were compared and analyzed.[Results]Carboxymethylated wheat bran dietary fiber(CWBDF)with a degree of substitution of 0.16 was successfully prepared,and its soluble dietary fiber content increased from 3.31%to 20.76%.The water-holding capacity,oil-holding capacity,and swelling capacity increased to 1.81,1.31,and 1.30 times those of the unmodified WBDF,respectively.The glucose adsorption capacity reached up to 2.18 times that of the unmodified WBDF.The cholesterol adsorption capacity was significantly enhanced and exhibited good pH independence.The DPPH and ABTS+radical scavenging rates were 1.33 and 1.53 times those of the unmodified WBDF,respectively.The total phenol content increased to 1.74 times that of the unmodified WBDF.Structural analysis revealed that cellulose and hemicellulose in CWBDF were degraded,the crystalline region was destroyed,and a loose porous structure with increased specific surface area was formed.[Conclusion]Carboxymethylation modification significantly increased the soluble dietary fiber content in WBDF and proved to be an effective approach to modifying its physical structure and enhancing its processing and functional properties.
吕强;韩小贤;李力;马森
河南工业大学 粮油食品学院,河南 郑州 450001河南工业大学 粮油食品学院,河南 郑州 450001河南工业大学 粮油食品学院,河南 郑州 450001河南工业大学 粮油食品学院,河南 郑州 450001
轻工纺织
羧甲基化改性麦麸膳食纤维理化特性功能特性结构特征
carboxymethylation modificationwheat bran dietary fiberphysicochemical propertyfunctional propertystructural characteristic
《轻工学报》 2026 (3)
62-75,14
河南省杰出青年科学基金资助项目(252300421032)国家自然科学基金面上项目(32272249)河南省高校科技创新人才项目(23HASTIT033)河南省科技研发计划联合基金项目(232103810060)
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