微波辅助合成石墨烯基材料及其储能应用研究进展OA
Research progress of microwave-assisted synthesis of graphene-based materials and the applications in energy storage
石墨烯基材料凭借高导电性、高热导率及优异的力学性能,在能源存储、电子器件、催化转化等领域具有不可替代的应用潜力.微波技术作为一种高效绿色的材料制备手段,具有加热速率快、热量分布均匀、选择性强等显著优势,可有效提升石墨烯基材料的制备效率与综合性能,在其制备过程中占据重要地位.本文系统综述了微波技术在石墨烯基材料领域的研究进展.首先,阐述了微波处理石墨烯的原理与作用机制,明确了在微波作用下石墨烯不仅可以产生显著热效应以加速反应进程,在特定条件下还可诱发放电等离子体效应;其次,探讨了微波技术在石墨烯基材料处理中的典型反应类型,包括石墨烯本体的改性、石墨烯功能化掺杂、石墨烯基复合材料的构建,并分析了石墨烯微波放电等离子体的辅助反应;随后,总结了微波处理后的石墨烯基材料在超级电容器、电池、储热装置等领域的应用现状与性能优势;最后,指出了微波技术在石墨烯基材料制备中的未来发展方向.
Graphene-based materials show irreplaceable application potential in energy storage,electronic devices,and catalytic conversion,due to their high electrical/thermal conductivity and excellent mechanical properties.As an efficient and eco-friendly preparation method,microwave technology features rapid heating,uniform heat distribution and strong selectivity,which can effectively enhance the preparation efficiency and overall performance of graphene-based materials,thus playing an important role in their fabrication.The research progress of microwave technology in graphene-based materials was systematically reviewed in the paper.Firstly,the principles and mechanisms of microwave treatment of graphene were expounded,confirming that under microwave irradiation,graphene not only produces significant thermal effects to accelerate reactions,but also induces discharge plasma effects under specific conditions for material modification.Secondly,typical microwave-assisted reactions,including intrinsic graphene modification,functional doping,and composite construction were discussed,while the auxiliary effect of microwave discharge plasma was analyzed.Subsequently,the application status and performance advantages of microwave-treated graphene-based materials in supercapacitors,batteries,and thermal storage devices were summarized.Finally,the future development directions of microwave technology in this field were identified.
邓乐萍;于琳竹;赵斌;沈飞;韩晓刚
西安交通大学 电气工程学院,陕西 西安,710115西安交通大学 电气工程学院,陕西 西安,710115西安交通大学 电气工程学院,陕西 西安,710115西安交通大学 电气工程学院,陕西 西安,710115西安交通大学 电气工程学院,陕西 西安,710115
化学化工
微波石墨烯热效应微波放电等离子体储能
microwavegraphenethermal effectmicrowave discharge plasmaenergy storage
《中南大学学报（自然科学版）》 2026 (4)
1509-1520,12
陕西省自然科学基础研究计划项目(2019JLZ-10)陕西省重点研发计划项目(2022GXLH-01-23)(Project(2019JLZ-10)supported by the Natural Science Basic Research Plan of Shaanxi ProvinceProject(2022GXLH-01-23)supported by the Key Research and Development Program of Shaanxi Province)
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