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纸张老化过程的检测技术与纤维素降解演化方程的研究进展OA

Advances in Detection Techniques and Cellulose Degradation Evolution Equations Based on Paper Aging Process

中文摘要英文摘要

老化降解是纸张不可逆的自然现象,也是影响纸质文献保存与物证鉴定的重要因素.纸张的主要成分木质纤维素在纸张的耐久性与老化过程中扮演关键角色.本文介绍了木质纤维素在纸张老化过程中的化学机理,系统梳理了近10年来用于纸张老化过程中微观结构检测的光谱与色谱技术,通过与机器学习、化学计量学等前沿领域互相结合深入剖析纸张的老化过程.总结了国内外在纤维素老化降解研究领域提出的多种降解演化方程,归纳纸张在老化过程中的变化规律及其对耐久性的影响.旨在从表征技术与动力学层面阐明近年来基于纸张老化机理研究及规律的关键进展,为纸质文献、司法物证的老化评估提供了理论支撑和技术路径.

Aging degradation is an irreversible natural phenomenon of paper,but also an important factor affecting the preservation of paper documents and identification of physical evidence.Lignocellulose,the main component of paper,plays a key role in the durability and aging process of paper.This paper introduces the chemical mechanism of lignocellulose in the aging process of paper,and systematically combs through the detection technology of microstructure in the aging process of paper in recent years,and deeply analyzes the aging process of paper by combining with machine learning and other cutting-edge fields.We also summarize a variety of kinetic models proposed in the field of cellulose aging and degradation research at home and abroad,and summarize the changing law of paper in the aging process and its impact on durability.It aims to elucidate the key progress in recent years based on the research of paper aging mechanism and law from the level of characterization technology and dynamics,and provide theoretical support and technical path for the aging assessment of paper documents and judicial exhibits.

叶祯;赵鹏程;陈伟;张祉悦;李宗航;刘松;彭国彬

中国刑事警察学院刑事科学技术学院,沈阳 110854中国刑事警察学院刑事科学技术学院,沈阳 110854中国刑事警察学院经济犯罪侦查学院,沈阳 110854中国刑事警察学院刑事科学技术学院,沈阳 110854中国刑事警察学院刑事科学技术学院,沈阳 110854中国刑事警察学院刑事科学技术学院,沈阳 110854中国刑事警察学院刑事科学技术学院,沈阳 110854

化学化工

纸张老化木质纤维素表征技术降解演化方程

Paper agingLignocelluloseCharacterization techniquesDegradation evolution equation

《应用化学》 2026 (5)

663-676,14

公安部科技强警基础专项(Nos.2022JC03,2023JC05)资助 Supported by the Ministry of Public Security Science and Technology Strengthening Police Basic Work Plan Project(Nos.2022JC03,2023JC05)

10.19894/j.issn.1000-0518.250233

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