焦炭/黄铁矿强化微生物燃料电池-人工湿地脱氮产电性能OA
Enhancement of nitrogen removal and power generation by coke/pyrite microbial fuel cell-constructed wet-land
微生物燃料电池-人工湿地(MFC-CW)因能够同时实现污染物去除与资源化利用而受到广泛关注.本研究以废焦炭和黄铁矿作为混合阳极填料构建了焦炭/黄铁矿强化MFC-CW系统(Mix-MFC-CW),并以黄铁矿单一阳极填料的MFC-CW系统(Py-MFC-CW)作对比,以探究焦炭与黄铁矿混合作为阳极填料是否能增强系统性能.结果表明,焦炭的介入使混合阳极层增加了微孔结构和比表面积,使系统的铵氮和总无机氮去除效率显著提高,分别达89.84%±1.63%和87.82%±1.58%,同时产电性能得到进一步提升,其最大输出电压和功率密度分别达到666 mV和1.18 mW·m-3.高通量测序结果显示,Py-MFC-CW在磷去除方面具有一定优势,这可能与系统中norank_o__Run-SP154的丰度较高有关.相比之下,在Mix-MFC-CW中,如Thio-thrix、Candidatus_Competibacter 和 Thauera 等反 硝化细菌丰度高于 Py-MFC-CW.因此,Mix-MFC-CW 有望成为一种具有竞争力的技术,同时提高脱氮和发电的性能.
Microbial fuel cell-constructed wetland(MFC-CW)is considered an environment-friendly and sustain-able technology to simultaneously purify water and generate bioelectricity.In this study,two MFC-CWs,including a coke/pyrite-based system(Mix-MFC-CW)and a pyrite-based system(Py-MFC-CW),were constructed to explore the role of coke and pyrite as mixed anode materials in enhancing system performance.Results showed that the in-corporation of coke increased the microporous structure and specific surface area of the anode region,significantly enhancing the removal efficiency of ammonium nitrogen(89.84%±1.63%)and total inorganic nitrogen(87.82%±1.58%),as well as electricity generation.The maximum output voltage and power density reached 666 mV and 1.18 mW·m-3,respectively.High-throughput sequencing results showed that Py-MFC-CW exhibited advantage in phosphorus removal,which may be related to the higher abundance of norank_o__Run-SP154.In contrast,the abundances of denitrifying bacteria such as Thiothrix,Candidatus_Competibacter,and Thauera were higher in Mix-MFC-CW than in Py-MFC-CW.Therefore,Mix-MFC-CW would be a competitive technology facilitating both nitro-gen removal and electricity generation.
张雪婷;汪茂森;秦杨毅;牛玉龙;樊鸿轩;黄亚飞;候悦林;吕健翔;杜京京
郑州轻工业大学材料与化学工程学院,郑州 450001郑州轻工业大学材料与化学工程学院,郑州 450001郑州轻工业大学材料与化学工程学院,郑州 450001郑州轻工业大学材料与化学工程学院,郑州 450001郑州轻工业大学材料与化学工程学院,郑州 450001郑州轻工业大学材料与化学工程学院,郑州 450001郑州轻工业大学材料与化学工程学院,郑州 450001郑州轻工业大学材料与化学工程学院,郑州 450001郑州轻工业大学材料与化学工程学院,郑州 450001||环境污染治理与生态修复河南省协同创新中心,郑州 450001
微生物燃料电池-人工湿地焦炭黄铁矿脱氮产电
microbial fuel cell-constructed wetlandcokepyritenitrogen removalelectricity generation
《生态学杂志》 2026 (5)
1616-1622,7
国家自然科学基金项目(32271701)、河南省优秀青年自然科学基金项目(232300421103)、河南省高校科技创新人才计划(24HASTIT027)资助.
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