还原糖种类对豆粕酶解物美拉德反应产物结构和风味特性的影响OA
Effect of Reducing Sugar Type on Structure and Flavor Characteristics of Maillard Reaction Products from Enzymatically Hydrolyzed Soybean Meal
本实验研究木糖、核糖、葡萄糖、果糖和半乳糖对豆粕酶解物美拉德反应产物(Maillard reaction products,MRPs)结构和风味特性的影响.褐变程度和紫外光谱分析显示,戊糖反应活性大于己糖,醛糖反应活性大于酮糖.荧光光谱分析显示,与豆粕酶解物相比,MRPs的荧光强度增强;红外光谱显示,与豆粕酶解物相比,MRPs吸收峰强度发生变化.分子质量结果显示,MRPs主要为分布在128~500 Da和500~1 000 Da的组分.核糖MRPs(R-MRPs)中苦味氨基酸和鲜味氨基酸含量较高,分别为9.29 mg/g和3.60 mg/g,戊糖MRPs的鲜味值、丰富度和苦味改善效果优于己糖MRPs.挥发性物质分析显示,R-MRPs中呋喃类、吡嗪类、酮类和醛类化合物含量最高,表现出更浓郁的焦糖香、坚果味和烤肉味.此外,利用R-SBMH体系成功制备了浓香大豆油,结果表明该反应体系在赋予油脂浓郁风味的同时,油脂的脂肪酸组成及理化指标仍保持良好的稳定性与安全性.
The effects of xylose,ribose,glucose,fructose,and galactose on the structural and flavor properties of Maillard reaction products(MRPs)derived from enzymatically hydrolyzed soybean meal were investigated.The extent of browning and ultraviolet(UV)spectroscopy analysis indicated that pentose exhibited higher reactivity than hexose,and aldose demonstrated greater reactivity than ketoses.Fluorescence spectroscopy analysis revealed an increase in the fluorescence intensity of MRPs,while infrared spectroscopy indicated alterations in absorption peak intensities of MRPs,compared with soybean meal hydrolysate.The molecular masses of MRPs were mainly distributed in the ranges of 128-500 and 500-1 000 Da.In addition,the contents of bitter amino acids and umami amino acids in ribose-derived MRPs(R-MRPs)were relatively high,at 9.29 and 3.60 mg/g,respectively.Pentose-derived MRPs exhibited superior umami value,richness value and lower bitterness compared with hexose-derived MRPs.Furans,pyrazines,ketones,and aldehydes were the most abundant volatile substance in R-MRPs,presenting stronger caramel,nutty and grilled meat-like aromas.Furthermore,strong-flavored soybean oil was successfully prepared using the ribose-soybean meal hydrolysate(SBMH)system,indicating that while the system imparted a rich flavor to the oil,the fatty acid composition and physicochemical indices of the oil remained stable and safe.
张赫;王雯;李中宾;王旭;于坤弘;于殿宇;王立琦
哈尔滨商业大学食品工程学院,黑龙江 哈尔滨 150028黑龙江省农投生物产业投资有限公司,黑龙江 哈尔滨 150090大兴安岭地区农业林业科学研究院,黑龙江 大兴安岭 165000哈尔滨商业大学食品工程学院,黑龙江 哈尔滨 150028黑龙江北大荒丰威食品有限公司,黑龙江 哈尔滨 150060黑龙江北大荒丰威食品有限公司,黑龙江 哈尔滨 150060哈尔滨商业大学食品工程学院,黑龙江 哈尔滨 150028
化学化工
豆粕美拉德反应美拉德反应产物风味特性结构特性
soybean mealMaillard reactionMaillard reaction productsflavor characteristicsstructural characteristics
《食品科学》 2026 (10)
97-104,8
黑龙江省"双一流"学科协同创新成果项目(LJGXCG2023-031)"十四五"国家重点研发计划子课题(2024YFD2100305-2)
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