超声辅助辛烯基琥珀酸酐改性小米淀粉稳定Pickering乳液及其负载姜黄素的分析OA
Stabilization and Curcumin-Loading Capacity of Pickering Emulsions Using Ultrasonic-Assisted Octenyl Succinic Anhydride-Modified Millet Starch
以小米淀粉为原料,经超声预处理后制备辛烯基琥珀酸酐(octenyl succinic anhydride,OSA)酯化改性小米淀粉,探究淀粉颗粒质量浓度和油水比对Pickering乳液稳定性的影响,并通过体外模拟消化实验评价Pickering乳液作为姜黄素递送载体的潜力.结果表明,随着淀粉颗粒质量浓度的增加,OSA小米淀粉稳定Pickering乳液粒径显著减小(从2 051.67 nm降至720.83 nm),乳化指数和表观黏度增大,稳定性增强,在质量浓度为5 g/100 mL时达到基本稳定状态;同时,随着油相比例的增加,乳液粒径增大(从638.11 nm增至2 967.35 nm),乳化指数、表观黏度和稳定性亦随之提高.与小米淀粉相比,OSA小米淀粉稳定的Pickering乳液对姜黄素的负载率和体外生物可及性分别提升至90.38%和23.49%,并表现出更高的游离脂肪酸释放率和贮藏稳定性.综上,OSA小米淀粉稳定的Pickering乳液是一种保护与递送姜黄素等生物活性物质的有效载体.
In this study,octenyl succinic anhydride(OSA)-modified millet starch was prepared from millet starch via ultrasonic pretreatment.The effects of starch particle concentration and oil-to-water ratio on the stability of Pickering emulsions were investigated,and the potential of Pickering emulsions as curcumin delivery carriers was evaluated through in vitro simulated digestion experiments.The results showed that with increasing starch particle concentration,the particle size of OSA-modified millet starch-stabilized Pickering emulsions decreased significantly(from 2 051.67 to 720.83 nm),the emulsification index and apparent viscosity increased,and the stability improved,reaching a basically stable state at a concentration of 5 g/100 mL.In addition,with the increase in oil phase ratio,the particle size of emulsions increased(from 638.11 to 2 967.35 nm),accompanied by corresponding improvements in the emulsification index,apparent viscosity and stability.In comparison to native starch-stabilized Pickering emulsion,the Pickering emulsion stabilized by OSA-modified millet starch exhibited higher curcumin loading capacity and in vitro bioaccessibility(90.38%and 23.49%,respectively)along with improved free fatty acid release and storage stability.Therefore,Pickering emulsions stabilized by OSA-modified millet starch are an effective carrier for protecting and delivering bioactive substances such as curcumin.
刘佳佳;张艺檬;闫倩倩;岳雨含;刘元宏;王文涛;孙圣麟
山东农业大学食品科学与工程学院,山东 泰安 271018山东农业大学食品科学与工程学院,山东 泰安 271018山东医药技师学院生物与食品科学系,山东 泰安 271000山东农业大学食品科学与工程学院,山东 泰安 271018山东农业大学食品科学与工程学院,山东 泰安 271018山东农业大学食品科学与工程学院,山东 泰安 271018山东农业大学食品科学与工程学院,山东 泰安 271018
轻工纺织
小米淀粉辛烯基琥珀酸酐酯化改性Pickering乳液姜黄素包埋
millet starchoctenyl succinic anhydride esterification modificationPickering emulsioncurcuminencapsulation
《食品科学》 2026 (10)
75-84,10
山东省重点研发计划(重大科技创新工程)项目(2024CXGC010917)
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