锂离子电池化成工艺的关键影响因素与优化策略分析OA
Key Influencing Factors and Optimization Strategy Analysis of Lithium-Ion Battery Formation Process
锂离子电池(LIBs)的化成工艺是生产过程中决定其倍率性能、循环寿命及安全性的关键步骤.本文系统梳理了化成工艺的基本流程与核心参数(如充电策略、电流密度、电压窗口、温度、压力及电解液组成等),并深入探讨了固态电解质界面(SEI)膜和阴极电解质界面(CEI)膜的形成机制及其动态演化规律.重点分析了各关键因素(包括化成电流密度与充电策略、截止电压、温度与压力、电解液配方及其组分如锂盐、溶剂、添加剂等)对界面膜结构、成分及电池性能的影响机制.研究表明,优化化成参数(如采用低电流密度、适宜温度、特定电解液添加剂等)可有效调控 SEI/CEI 膜的均匀性、稳定性及无机成分含量,从而提升电池的综合性能.本文总结的化成工艺影响因素及其作用机制,可为LIBs 化成工艺的优化设计提供理论依据和实践参考,并展望了未来结合计算电化学、先进表征与人工智能技术实现智能化工艺调控的发展方向.
The formation process of lithium-ion batteries(LIBs)is a critical manufacturing step that deter-mines the rate capability,cycle life,and safety.This paper systematically reviews the fundamental procedures and core parameters of the formation process(including charging protocols,current density,voltage window,temperature,pressure,and electrolyte composition),at the same time deeply investigating the formation mecha-nisms and dynamic evolution patterns of the solid electrolyte interphase(SEI)and cathode electrolyte inter-phase(CEI).Key influencing factors—such as formation current density,charging protocols,cut-off voltage,temperature,pressure,and electrolyte formulation(lithium salts,solvents,additives)—were analyzed for their impacts on interfacial film structure/composition and battery performance.Research demonstrates that opti-mized formation parameters(e.g.,low current density,moderate temperature,specific electrolyte additives)can effectively regulate the uniformity,stability,and inorganic component content of SEI/CEI films,thereby en-hancing overall battery performance.The summarized influencing factors and mechanisms provide theoretical foundations and practical references for LIBs formation process optimization.Future development directions are also proposed,integrating computational electrochemistry,advanced characterization techniques,and artificial intelligence to achieve intelligent process control.
吴启辉;樊晓红;黄晰;汪颖;蔡阳声;吴冠宏;李桂芳;陶明明;邓丁榕;曾叶
集美大学海洋装备与机械工程学院,福建 厦门 361021集美大学海洋装备与机械工程学院,福建 厦门 361021集美大学海洋文化与法律学院,福建 厦门 361021厦门新能安科技有限公司,福建 厦门 361000厦门新能安科技有限公司,福建 厦门 361000厦门新能安科技有限公司,福建 厦门 361000集美大学海洋装备与机械工程学院,福建 厦门 361021集美大学海洋装备与机械工程学院,福建 厦门 361021集美大学海洋装备与机械工程学院,福建 厦门 361021集美大学海洋装备与机械工程学院,福建 厦门 361021
化学化工
锂离子电池化成工艺固态电解质界面
lithium-ion batteriesformation processsolid electrolyte interphase
《集美大学学报(自然科学版)》 2026 (3)
344-357,14
国家自然科学基金面上项目(22172062)
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