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含三嗪环结构耐酸纳滤膜的制备及性能研究进展OA

Progress on preparation and performance of acid-resistant nanofiltration membranes with triazine ring structure

中文摘要英文摘要

三嗪环具有良好的机械性能、热稳定性以及酸稳定性,通过含三嗪环结构单体界面聚合制备的耐酸纳滤膜可用于酸性废水处理.为改善含三嗪环结构单体反应活性较低,以及含三嗪环结构耐酸纳滤膜渗透性及截留率之间存在的"Trade-off"效应等问题,研究人员采用多种方法提升复合膜分离性能.本文综述了近年来通过界面聚合法引入三嗪环结构制备耐酸纳滤膜的研究进展,从基于三聚氯氰有机相单体的界面聚合、基于含三嗪环结构水相单体的界面聚合以及含三嗪环结构单体界面聚合工艺的改进3个方面,综述了含三嗪环结构耐酸纳滤膜的结构及性能调控研究进展,并对该领域目前存在的问题及未来发展方向进行展望.

The triazine ring exhibits excellent mechanical properties,thermal stability,and acid stability.Acid-resistant nanofiltration membranes prepared via interfacial polymerization of triazine ring-containing monomers can be employed for treating acidic wastewater.To address issues such as the relatively low reactivity of triazine ring-containing monomers and the trade-off between permeability and rejection rate in acid-resistant nanofiltration membranes incorporating triazine ring structures,researchers have employed multiple approaches to enhance the separation performance of composite membranes.The research progress on the preparation of acid-resistant nanofiltration membranes by introducing triazine ring structures through interfacial polymerization in recent years was reviewed.Advances in three aspects were summarized:interfacial polymerization based on organic phase monomers of cyanuric chloride,interfacial polymerization based on aqueous phase monomers containing triazine ring structures,and process improvements for interfacial polymerization of triazine ring-containing monomers.Moreover,the existing problems and prospects for future development in this fieldwere expected.

柳小楼;李墨文;胡欣淼;阙勇;王嘉祎;郭红霞

北京工业大学 材料科学与工程学院,北京 100124北京工业大学 材料科学与工程学院,北京 100124北京工业大学 材料科学与工程学院,北京 100124北京化工大学 化学工程学院,北京 100029北京工业大学 材料科学与工程学院,北京 100124北京工业大学 材料科学与工程学院,北京 100124||北京工业大学 材料循环低碳再生全国重点实验室,北京 100124

资源环境

三嗪环结构单体界面聚合耐酸膜纳滤

triazine ring structuremonomerinterfacial polymerizationacid-resistant membranenanofiltration

《化工环保》 2026 (3)

312-320,9

国家自然科学基金面上项目(22178007).

10.3969/j.issn.1006-1878.2026.03.002

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