基于纳米压印和热调控转印的高分辨率量子点发光二极管OA
High-resolution Quantum Dot Light-emitting Diodes Based on Nanoimprint Lithography and Thermal-regulated Transfer Printing
量子点发光二极管(Quantum dot light-emitting diodes,QLEDs)具有高色纯度、宽色域和溶液加工兼容性等优势,被视为下一代高分辨率显示技术的重要发展方向.然而,如何在无损于量子点(Quantum dots,QDs)光学性能的前提下实现高分辨率图案化,仍是其走向实际应用的关键技术瓶颈.本文针对高分辨率QLEDs制备中的图案化难题,提出了一种基于纳米压印与热调控转印的新型图案化工艺.该方法通过硅模板压印在聚乙烯醇缩丁醛(PVB)表面构建蜂窝状微结构,并利用溶液润湿性控制量子点的选择性填充,再经由热调控转印过程,能够制备特征尺寸低至1.5 µm、分辨率为9 072像素每英寸(Pixel per inch,PPI)的高均匀性量子点阵列.通过采用更高分辨率的模板,我们还实现了最高25 400 PPI像素密度的量子点阵列.进一步地,我们通过在空穴传输层(Hole transport layer,HTL)上制备量子点阵列,成功制得了高分辨率红色QLEDs器件(9 072 PPI),其最大外量子效率(EQE)达10.91%,最大亮度为164 421 cd/m².本工作为高分辨率QLEDs的制备提供了一种工艺稳定、可重复的图案化新途径.
Quantum dot light-emitting diodes(QLEDs),renowned for their high color purity,wide color gamut,and solution processability,are considered a pivotal technology for next-generation high-resolution displays.Howev-er,achieving high-resolution patterning without compromising the optical properties of quantum dots(QDs)remains a critical challenge hindering their practical application.Addressing this patterning bottleneck in high-resolution QLEDs fabrication,this work presents a novel patterning strategy based on nanoimprint lithography and thermally regulated transfer printing.The proposed method involves fabricating honeycomb microstructures on a polyvinyl buty-ral(PVB)surface using a silicon template,followed by selective filling of QDs controlled by solution wettability.Through a subsequent thermal-regulated transfer process,highly uniform QDs arrays with a feature size as small as 1.5 µm and a resolution of 9 072 pixels per inch(PPI)are successfully prepared.By employing higher-resolution templates,we have further achieved QDs array with a maximum pixel density of 25 400 PPI.Furthermore,we suc-cessfully fabricated high-resolution red QLEDs device(9 072 PPI)by integrating the QDs array onto hole trans-port layer(HTL),achieving a maximum external quantum efficiency(EQE)of 10.91%and a peak luminance of 164 421 cd/m².This work provides a stable and reproducible patterning pathway for the fabrication of high-resolution QLEDs.
谢潇婷;林海燕;赵宇森;陈伟国;杨开宇
福州大学 物理与信息工程学院,福建 福州 350108福州大学 物理与信息工程学院,福建 福州 350108福州大学 物理与信息工程学院,福建 福州 350108福州大学 物理与信息工程学院,福建 福州 350108||中国福建省光电信息科技创新实验室,福建 福州 350108福州大学 物理与信息工程学院,福建 福州 350108||中国福建省光电信息科技创新实验室,福建 福州 350108
信息技术与安全科学
量子点发光二极管(QLEDs)高分辨率纳米压印热调控转印
quantum dot light-emitting diodes(QLEDs)high-resolutionnanoimprintthermal regulated transfer printing
《发光学报》 2026 (5)
846-853,8
国家重点研发计划(2022YFB3606500)国家自然科学基金(62575071,62305063)福建省自然科学基金(2023J01257) Supported by National Key R&D Program of China(2022YFB3606500)National Natural Science Foundation of China(62575071,62305063)Provincial Natural Science Foundation of Fujian(2023J01257)
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