铟化合物掺杂塑料闪烁体制备与性能研究OA
Preparation and Properties of Indium Compounds Doped Plastic Scintillators
塑料闪烁体具有低成本、环境稳定性好、易于大尺寸制备等优点,在辐射探测领域有着广泛的应用.常见的塑料闪烁体由于有效原子序数低,导致探测效率不足,限制了它们在高能辐射探测领域等进一步应用.已有多种方法将具有高有效原子序数的材料引入到塑料闪烁体中,其中有机重金属化合物由于具有有机物的部分性质,可以在聚合物基质中溶解,为提高塑料闪烁体的射线阻止能力和探测效率提供了一种更有效的途径.本文选用三(2,4-戊二酮酸)铟(Ⅲ)(In(acac)3)作为掺杂剂,首次成功制备了一系列不同In(acac)3掺杂浓度的塑料闪烁体,系统性研究了掺杂浓度对塑料闪烁体的光学和闪烁性能的影响.随着掺杂浓度的增加,塑料闪烁体的有效原子序数逐渐增加,吸收系数增大,但光产额逐渐降低.其中,质量分数3%In(acac)3掺杂塑料闪烁体在光产额和探测效率之间达到均衡状态,实现了伽马计数率的提升.
Plastic scintillators have been extensively used in the field of radiation detection due to their low cost,good environmental stability,and simple large-scale preparation.Common plastic scintillators generally have insuffi-cient detection efficiency due to their low effective atomic number,which limits their further application in high ener-gy radiation and other fields.There are various methods to introduce materials with high effective atomic number into plastic scintillators.Among them,organic heavy metal compounds,due to their partial properties as organic com-pounds,can dissolve in polymer matrices,providing a more effective way for plastic scintillators to improve radiation stopping power and detection efficiency.In this work,tris(2,4-pentanedionato)indium(Ⅲ)(In(acac)3)was select-ed as a dopant,plastic scintillators doped with different concentrations of In(acac)3 were successfully prepared for the first time,and the changes in optical and scintillation properties of plastic scintillators with different doping con-centrations were systematically studied.As the doping concentration increases,the effective atomic number and ab-sorption coefficient of the plastic scintillator gradually increase,while the light yield progressively decreases.Among them,mass fraction 3%In(acac)3 doped plastic scintillator achieves an optimal balance between light yield and de-tection efficiency,resulting in an enhanced gamma count rate.
李雯;陈楚鑫;李云云;李焕英;吴云涛
中国科学院上海硅酸盐研究所 功能晶体与器件全国重点实验室,上海 201899||中国科学院大学 材料科学与光电技术学院,北京 100049中国科学院上海硅酸盐研究所 功能晶体与器件全国重点实验室,上海 201899||中国科学院大学 材料科学与光电技术学院,北京 100049中国科学院上海硅酸盐研究所 功能晶体与器件全国重点实验室,上海 201899中国科学院上海硅酸盐研究所 功能晶体与器件全国重点实验室,上海 201899中国科学院上海硅酸盐研究所 功能晶体与器件全国重点实验室,上海 201899
数理科学
塑料闪烁体铟化合物光学性能闪烁性能
plastic scintillatorsindium compoundsoptical propertiesscintillation properties
《发光学报》 2026 (5)
736-743,8
广东省重点领域研发计划(2024B0101070003)国家自然科学基金(12575331,12305211,12575203) Supported by Guangdong S&T Programm(2024B0101070003)National Natural Science Foundation of China(12575331,12305211,12575203)
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