Metal-Organic Frameworks:Multifunctional Materials for High-Performance Zn-Halogen BatteriesOA
Aqueous zinc batteries are gaining attention as promising alternatives to Li-ion systems,owing to the increased need for safe and costeffective energy storage.Aqueous Zn-halogen batteries are particularly important because of their low cost and the abundance of precursors.However,critical challenges,such as the shuttle effect,sluggish redox kinetics,and dendrite growth,impede their practical development.Metal-organic frameworks(MOFs)with high porosity,ease of functionalization,and stability offer a multifunctional approach to overcome these limitations.This review systematically examines the advancements in MOF-based Zn-halogen batteries,focusing on their roles in different components of the battery,including the cathode,anode,and separator.This review also highlights the key design strategies for MOF-based materials and then examines the structure-performance relationships through advanced characterization and computational insights.The remaining challenges and future directions are also outlined.Overall,this review provides a roadmap for developing advanced MOF-based Zn-halogen batteries that combine high energy density and long-term durability for next-generation energy storage applications.
Ayesha Arif;Xinrui Yan;Adil Mansoor;Tazeen Fatima;Tayyaba Najam;Hassan Akhtar;Muhammad Sufyan Javed;Manzar Sohail;Muhammad Altaf Nazir;Jiantao Zai;Xiaowei Yang;Syed Shoaib Ahmad Shah
Catalysis and Surface Chemistry Laboratory,Department of Chemistry,School of Natural Sciences,National University of Sciences and Technology(NUST),Islamabad 44000,PakistanShanghai Electrochemical Energy Devices Research Center,School of Chemistry and Chemical Engineering,Shanghai Jiao Tong University,Shanghai 200240,People''s Republic of ChinaShenzhen Key Laboratory of Advanced Thin Films and Applications,College of Physics and Optoelectronic Engineering,Shenzhen University,Shenzhen,Guangdong 518060,People''s Republic of ChinaCatalysis and Surface Chemistry Laboratory,Department of Chemistry,School of Natural Sciences,National University of Sciences and Technology(NUST),Islamabad 44000,PakistanInstitute of Chemistry,The Islamia University of Bahawalpur,Bahawalpur 63100,PakistanNational Synchrotron Radiation Laboratory,Key Laboratory of Precision and Intelligent Chemistry,School of Nuclear Science and Technology,University of Science and Technology of China,Hefei,Anhui 230029,People''s Republic of ChinaInstitute of Carbon Neutrality,Zhejiang Wanli University,Ningbo 315100,People''s Republic of ChinaCatalysis and Surface Chemistry Laboratory,Department of Chemistry,School of Natural Sciences,National University of Sciences and Technology(NUST),Islamabad 44000,PakistanInstitute of Chemistry,The Islamia University of Bahawalpur,Bahawalpur 63100,PakistanShanghai Electrochemical Energy Devices Research Center,School of Chemistry and Chemical Engineering,Shanghai Jiao Tong University,Shanghai 200240,People''s Republic of ChinaShanghai Electrochemical Energy Devices Research Center,School of Chemistry and Chemical Engineering,Shanghai Jiao Tong University,Shanghai 200240,People''s Republic of ChinaCatalysis and Surface Chemistry Laboratory,Department of Chemistry,School of Natural Sciences,National University of Sciences and Technology(NUST),Islamabad 44000,Pakistan
信息技术与安全科学
Metal-organic frameworks(MOFs)Zinc-halogen batteriesShuttle effectPolyhalide confinementEnergy storage
《Nano-Micro Letters》 2026 (7)
P.485-539,55
PSFNSFC combined project funding PSF/NSFC-V/ENG/CNUST/36,22461142137NUST-flagship Project(FSP-23-03)Science and Technology Major Project of Shanghai.
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