首页|期刊导航|陕西科技大学学报|声共振协同化学糊化对淀粉性质的影响

声共振协同化学糊化对淀粉性质的影响OA

Effect of resonant acoustic mixing synergistic chemical gelatinization on starch properties

中文摘要英文摘要

声共振作为一种新型物理场,目前对淀粉化学糊化的影响尚不明确.本研究在室温条件下,以马铃薯(B型)、玉米(A型)淀粉为研究对象,在声共振处理下采用4 mol/L的CaCl2溶液构建化学糊化体系,并以磁力搅拌处理为对照组.结果表明:声共振处理可通过增强CaCl2溶液对淀粉颗粒表面的侵蚀作用,显著提高马铃薯淀粉与玉米淀粉的化学糊化速率,使二者达到相同糊化程度的时间较对照组分别缩短30%和31%.黏度分析显示所有残存颗粒黏度降低,与原淀粉的峰值黏度相比,声共振处理的马铃薯残存颗粒降低了54%、玉米残存颗粒降低23%;更低的回生值表明声共振可改善淀粉的老化.X-射线衍射、傅里叶红外和拉曼分析均证实声共振不改变残存颗粒的晶型及官能团,但可提高残存颗粒的结构有序度.声共振可改变颗粒的流变行为,相较于对照组,马铃薯残存颗粒的G'降低17.9%、G"降低16.4%,而玉米残存颗粒的G'比对照组高出12.1%、G"高出16.9%,不同晶型淀粉因结构差异呈现出不同的变化规律.本研究阐明了声共振辅助淀粉表面化学糊化的作用机理,揭示了其对马铃薯、玉米淀粉理化性质调控的内在规律,为淀粉的绿色高效改性提供了新思路.

As a new type of physical field,the effect of resonant acoustic mixing on the chemical ge-latinization of starch is still unclear.In this study,potato(B-type)and corn(A-type)starches were used as research objects to construct a chemical gelatinization system using 4 mol/L CaCl2 solution under resonant acoustic mixing treatment at room temperature,and magnetic stirring treatment was used as the control group.The results showed that resonant acoustic mixing treatment could signifi-cantly increase the chemical gelatinization rate of potato starch and corn starch by enhancing the ero-sion of CaCl2 solution on the surface of starch granules,and the time to reach the same gelatinization degree was shortened by 30%and 31%,respectively,compared with the control group.Viscosity a-nalysis showed that the viscosity of all residual granules decreased.Compared with the peak viscosity of native starch,the residual granules of potato treated by resonant acoustic mixing decreased by 54%and the residual granules of corn decreased by 23%.The lower retrogradation value indicates that resonant acoustic mixing can improve the aging of starch.X-ray diffraction,Fourier transform infrared spectroscopy and Raman analysis confirmed that resonant acoustic mixing did not change the crystal form and functional groups of the residual particles,but could improve the structural or-der of the residual particles.Resonant acoustic mixing can change the rheological behavior of gran-ules.Compared with the control group,the G'of potato residual granules decreased by 17.9%and G"decreased by 16.4%,while the G'of corn residual granules was 12.1%higher than that of the control group and the G"was 16.9%higher.Starches with different crystal forms exhibit different variation rules due to structural differencs,this study clarified the mechanism of surface chemical ge-latinization of starch assisted by resonant acoustic mixing,revealed the inherent law of its regulation on the physical and chemical properties of potato and corn starch,and provided a new idea for the green and efficient modification of starch.

霍一凡;黄峻榕;王雪;于肖;蒲华寅;曹云刚

陕西科技大学食品科学与工程学院,陕西西安 710021陕西科技大学食品科学与工程学院,陕西西安 710021陕西科技大学食品科学与工程学院,陕西西安 710021陕西科技大学食品科学与工程学院,陕西西安 710021陕西科技大学食品科学与工程学院,陕西西安 710021陕西科技大学食品科学与工程学院,陕西西安 710021

轻工纺织

化学糊化声共振残存颗粒多晶型淀粉

chemical gelatinizationresonant acoustic mixingremaining granulespolymor-phic starch

《陕西科技大学学报》 2026 (3)

53-61,9

国家自然科学基金项目(31772012)陕西省重点研发计划一般项目(2023-YBNY-175)陕西省西安市科技计划项目(24NYGG0055)

评论