协效阻燃聚丙烯复合材料的制备及性能研究OA
Preparation and Performance Study of Synergistic Flame Retardant Polypropylene Composites
利用阴离子表面活性剂油酸钠与硅烷偶联剂(KH550)对无机阻燃剂氢氧化镁(MH)进行表面改性,再将改性氢氧化镁(MMH)与乙酸纤维(CA)复配,与聚丙烯(PP)共混,制备阻燃PP复合材料,研究该复合材料的阻燃性能与力学性能.结果表明:在PP基体中同时引入MMH和CA可使复合材料具有良好的阻燃性能、热稳定性能及力学性能,当MMH/CA添加质量分数为40%时(MMH和CA质量比为7∶1),复合材料的极限氧指数可达28.9%,UL-94测试达到V-0级,拉伸强度与抗冲击强度分别达到24.9 MPa和11.7 kJ/m2,力学性能优于单独加入CA或MMH的阻燃PP复合材料,说明MMH与CA可形成良好的协效阻燃效果.
The inorganic flame retardant magnesium hydroxide(MH)was surface-modified using anionic surfactant sodium oleate and silane coupling agent(KH550).The modified magnesium hydroxide(MMH)was then compounded with cellulose acetate(CA)and blended with polypropylene(PP)to prepare flame retardant PP composites,and the flame retardancy and mechanical properties of the composites were investigated.The results showed that the simultaneous incorporation of MMH and CA into the PP matrix endowed the composites with favorable flame retardancy,thermal stability,and mechanical properties.When the mass fraction of MMH/CA was 40%(with a mass ratio of MMH to CA of 7∶1),the limiting oxygen index of the composite reached 28.9%,the UL-94 rating achieved V-0 level,and the tensile strength and impact strength reached 24.9 MPa and 11.7 kJ/m2,respectively.The mechanical properties were superior to those of flame retardant PP composites containing CA or MMH alone,indicating that MMH and CA exhibited good synergistic flame retardant effects.
宋肄业;金怡君;沙君勐;许锦超
常州大学怀德学院机械与材料工程系,江苏 靖江 214500常州大学怀德学院机械与材料工程系,江苏 靖江 214500常州大学怀德学院机械与材料工程系,江苏 靖江 214500常州大学怀德学院机械与材料工程系,江苏 靖江 214500
通用工业技术
氢氧化镁乙酸纤维聚丙烯阻燃性能力学性能
Magnesium hydroxideCellulose acetatePolypropyleneFlame retardancyMechanical properties
《塑料科技》 2026 (4)
37-41,5
泰州市科技支撑计划(社会发展)项目(TSD2022512)江苏省高校"青蓝工程"优秀青年骨干教师资助项目(苏教师函[2023]27号)泰州市第六期"311高层次人才培养专项"(泰人才办[2023]10号)
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