析出相对317L不锈钢力学性能的影响OACHSSCD
Effects of precipitation phases on the mechanical properties of 317L stainless steel
317L不锈钢作为一种高Mo含量的奥氏体不锈钢,广泛应用于石油化工、化学及核工程等;然而,在长期高温服役过程中,材料内部易析出σ相、碳化物等硬脆相,导致力学性能退化,威胁工程结构的安全性.本文针对317L不锈钢,探究时效温度(750和850 ℃)及时间(25~500 h)对析出相种类、析出相含量和力学性能的影响.结果表明:钢材中残存的δ铁素体为主要析出相(σ相)的快速形核创造了条件,析出量随时间的延长和温度的增加显著增多.析出相引发硬化效应,致使时效后材料的硬度大幅提升,硬度变化与析出相占比呈正相关性;并且材料的塑韧性严重劣化.析出相(特别是σ相)既能通过钉扎位错强化基体,又能作为脆性裂纹源导致晶界脆化,促使断裂模式从塑韧性断裂变为脆性断裂.
317L stainless steel is a high-molybdenum austenitic stainless steel widely used in petrochemical,chemical,and nuclear engineering.However,during prolonged high-temperature service,hard and brittle phases,such as σ phase and carbides,can precipitate.This leads to a degradation of mechanical properties and threatens the safety of engineering structures.This study examines the impact of aging temperature(750 and 850 ℃)and aging time(25-500 h)on the types and amounts of precipitated phases,as well as on the mechanical properties of 317L stainless steel.The results show that the residual δ-ferrite in steel promotes rapid nucleation of the main precipitation phase(σ phase),and the amount of precipitation increases significantly with longer aging time and temperatures.Precipitation induces hardening,resulting in a significant increase in the hardness of the material after aging.The hardness change is positively correlated with the volume fraction of precipitation phases.However,the ductility and toughness of the material are seriously deteriorated.The precipitation phases(especially σphase)can not only strengthen the matrix by pinning dislocations,but also act as sites for brittle cracks,leading to grain boundary embrittlement.This results in a transition from ductile to brittle fracture.
赵思源;李喆;唐建群;巩建鸣
南京工业大学机械与动力工程学院,江苏南京 211800南京工业大学机械与动力工程学院,江苏南京 211800南京工业大学机械与动力工程学院,江苏南京 211800南京工业大学机械与动力工程学院,江苏南京 211800
通用工业技术
317L不锈钢δ铁素体析出相力学性能时效
317L stainless steelδ-ferriteprecipitation phasemechanical propertiesaging
《南京工业大学学报(自然科学版)》 2026 (2)
213-221,9
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