硝酸异丙酯和铝粉对正庚烷云雾点火特性的影响OA
Effects of Isopropyl Nitrate and Aluminum Powder on the Ignition Characteristics of n-Heptane Fuel Mists
为了探究敏化剂(硝酸异丙酯)和高能金属粉(铝粉)对典型烷烃燃料(正庚烷)/空气云雾的点火特性的影响,揭示敏化剂和高能金属粉对燃料空气炸药(FAE)点火敏感性的调控作用,在6.28L爆炸罐内进行了喷雾-点火的同步控制,采集了云雾点火过程中的压力变化和瞬态形貌,获取了正庚烷混入不同质量分数的硝酸异丙酯和铝粉形成的多相云雾的点火特性.结果表明,正庚烷云雾的最小点火能随化学计量比的提高总体呈上升趋势,且表现出非线性的变化特征.硝酸异丙酯(IPN)的加入显著降低了混合云雾的最小点火能,其中每增加质量分数10%的IPN,最小点火能分别下降约14%、21%和10%.在正庚烷体系中加入铝粉后,添加少量(质量分数10%)铝粉会降低云雾最小点火能,但当质量分数达到20%~30%时,固相颗粒占比增加导致能量耗散与空气不足,使最小点火能反而升高.云雾爆炸的峰值压力表明各燃料均在化学计量比附近达到峰值;在φ=1.0条件下,纯正庚烷云雾的最大升压速率为22 230kPa/s,加入质量分数10%或20%IPN后分别提高至35 920kPa/s和59 300kPa/s,而当IPN质量分数增至30%时则回落至28 384kPa/s.加入铝粉后,随着铝粉质量分数由10%增至30%时,最大升压速率由27 482 kPa/s 增至 44 770 kPa/s.
To investigate the effects of the sensitizer,isopropyl nitrate(IPN),and the high-energy metal powder,aluminum(Al),on the ignition characteristics of typical alkane fuel n-heptane/air mists,and to reveal their regulatory roles in the ignition sensitivity of fuel-air explosives(FAEs),synchronized spray-ignition experiments were carried out in a 6.28L explosion vessel.Pressure evolution and transient flame morphology during mist ignition were recorded.And the ignition characteristics of multi-phase mists formed by n-heptane blended with different proportions of IPN and Al were obtained.The results show that the minimum ignition energy(MIE)of n-heptane mist generally increases with increasing the equivalence ratio,exhibiting a nonlin-ear variation trend.The addition of IPN significantly reduces the MIE of the mixed mist,with the MIE decreasing by approxi-mately 14%,21%,and 10%for every 10%increase in IPN mass fraction,respectively.After the addition of Al to the n-heptane system,a small amount of Al(10%)reduce the MIE of the mist.However,when the Al mass fraction reaches 20%—30%,the increased proportion of solid particles leads to greater energy dissipation and insufficient air,causing the MIE to rise instead.The peak explosion pressure results indicate that all fuel mixtures reach their maximum values near the stoichio-metric equivalence ratio.Under the condition of φ=1.0,the maximum pressure rise rate of pure n-heptane mist is 22230kPa/s.After 10%or 20%IPN is added,the maximum pressure rise rate increases to 35920kPa/s and 59300kPa/s,respectively,but then decreases to 28384kPa/s when the IPN mass fraction further increases to 30%.After the addition of Al,the maximum pressure rise rate increases from 27482kPa/s to 44770kPa/s as the Al mass fraction increases from 10%to 30%.
郭祎嘉;常鹏程;王玮;李建;王伯良
南京理工大学安全科学与工程学院,江苏南京 210094山西江阳化工有限公司,山西 太原 030041山西江阳化工有限公司,山西 太原 030041南京理工大学化学与化工学院,江苏南京 210094南京理工大学化学与化工学院,江苏南京 210094
军事科技
物理化学点火特性正庚烷硝酸异丙酯铝粉爆炸压力燃料空气炸药
physical chemistryignition characteristicsn-heptaneisopropyl nitratealuminum powderexplosion pressurefuelair explosive
《火炸药学报》 2026 (4)
405-416,12
中央高校基本科研务费专项资金资助(No.30925010307)
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