含AlB2@PVDF/AlLi2复合燃料的CL-20基炸药安全与能量特性OA
Safety and Energy Characteristics of CL-20-Based Explosive Containing AlB2@PVDF/AlLi2 Composite Fuel
为了提升CL-20基混合炸药的爆轰能量水平,采用聚偏氟乙烯包覆二硼化铝(AlB2@PVDF)与高活性铝锂合金粉(AlLi2)组成复合燃料,将其分别引入CL-20基浇注和压装两种炸药体系中,系统测试了 AlB2@PVDF/AlLi2复合燃料与炸药各组分的相容性、安定性、机械感度、爆热、爆速以及静爆冲击波超压等性能参数,并与等燃料质量分数的传统CL-20基含铝炸药进行对比.结果表明,AlB2@PVDF/AlLi2复合燃料与两种炸药体系相容性良好,真空安定性符合要求;含AlB2@PVDF/AlLi2复合燃料炸药的机械感度略高于对应含铝炸药,但仍低于40%,满足实际应用需求.相比于等燃料质量的含铝炸药,浇注体系和压装体系AlB2@PVDF/AlLi2复合燃料炸药的爆热分别提升8.20%和13.09%,爆速分别提高41m/s和91m/s.静爆实验进一步显示,在相同距离下两种体系含AlB2@PVDF/AlLi2复合燃料炸药产生的冲击波超压均高于对应的含铝炸药,尤其在近场表现突出:浇注体系在2m处超压提升约30.7%,压装体系在2m处提升约8.3%.
To enhance the detonation performance of CL-20-based composite explosives,the composite fuel consisting of pol-yvinylidene fluoride-coated aluminum diboride(AlB2@PVDF)and highly reactive aluminum-lithium alloy powder(AlLi2)were introduced into CL-20-based cast and pressed explosive systems,respectively.Systematically tests were conducted on the com-patibility,stability,mechanical sensitivity,heat of detonation,velocity of detonation,and static explosion shockwave over-pressure of the composite fuel with other explosive components.Comparisons were made with traditional CL-20-based alumi-nized explosives containing the same mass fraction of fuel.The results indicate good compatibility between the composite fuel and both explosive systems,with vacuum stability meeting requirements.The mechanical sensitivity of the explosives containing the composite fuel is slightly higher than that of aluminized counterparts but remains below 40%,satisfing practical application needs.Compared to aluminized explosives with equal fuel mass,the heat of detonation for the cast and pressed systems contai-ning the composite fuel increased by 8.20%and 13.09%,respectively,while the velocity of detonation increased by 41 m/s and 91 m/s,respectively.Static explosion experiments further showed that the shockwave overpressure generated by both sys-tems containing the composite fuel at the same distance were higher than that of the corresponding aluminized explosives,par-ticularly notable in the near field:the cast system exhibited an approximately 30.7%increase in overpressure at 2m,and the pressed system showed an approximately 8.3%increase.
王江峰;赵婉君;欧亚鹏;郭学永;王维维;焦清介
北京理工大学爆炸科学与技术国家重点实验室,北京 100081北京理工大学爆炸科学与技术国家重点实验室,北京 100081北京理工大学爆炸科学与技术国家重点实验室,北京 100081北京理工大学爆炸科学与技术国家重点实验室,北京 100081重庆红宇精密工业集团有限公司,重庆 402760北京理工大学爆炸科学与技术国家重点实验室,北京 100081
军事科技
物理化学AlB2@PVDF/AlLi2复合燃料CL-20基炸药金属燃料冲击波超压
physical chemistryAlB2@PVDF/AlLi2 composite fuelCL-20-based explosivesmetal fuelshockwave overpres-sure
《火炸药学报》 2026 (4)
363-369,7
国家自然科学基金(No.22105067)
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