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金属氧化物及金属氟化物改性硼粉的燃烧性能研究进展OA

Research Progress on the Combustion Performance of Boron Powders Modified with Metal Oxides and Metal Fluorides

中文摘要英文摘要

为解决金属燃料硼粉(B)点火困难、燃烧效率低、能量释放不完全的问题,以去除其表面致密的氧化层(B2O3)为核心,总结了近年来以金属氧化物(MxOy)(如Bi2O3、CuO、NiO、TiO2、SnO2、MoO3等)和金属氟化物(MxFy)(如LiF、BiF3、FeF3、CoF2等)在改善B点火和燃烧性能的研究,分析了不同改性材料对B燃烧性能的影响,对比了不同材料改性B的点火和燃烧性能的优缺点,揭示了改性材料对B的作用机制.指出当前面临的挑战:需借助"微观-细观-宏观"的多尺度计算模拟与机器学习模型,建立改性材料与 B燃烧性能之间的构效关系,并致力于面向多组分协同复合包覆、纳米结构化以及新型反应体系设计等综合调控和优化策略,为实现B燃料的高效燃烧、可控应用提供理论依据.附参考文献87篇.

To address the challenges of difficult ignition,low combustion efficiency,and incomplete energy release of boron(B)powder as a metal fuel,the removal of the inherent dense oxide layer(B2O3)on B surface was focused.The recent ad-vances by using metal oxides(MxOy)(e.g.,Bi2O3,CuO,NiO,TiO2,SnO2,MoO3)and metal fluorides(MxFy)(e.g.,LiF,BiF3,FeF3,CoF2)to improve the ignition and combustion performance of B are summarized.The effects of different modifiers on the combustion of B are analyzed,and the advantages and disadvantages of various modified B in terms of ignition and com-bustion performance are compared.The mechanisms of modified B by the modifiers are elucidated.Current challenges are i-dentified,including the need to establish structure-performance relationships between modifiers and B combustion through multi-scale computational simulations from micro-to meso-and macro-scale combined with machine learning models.Furthermore,comprehensive strategies such as synergistic multi-component composite coating,nano-structuring,and novel reactive system design should be pursued to optimize B combustion.These efforts aim to provide a theoretical foundation for achieving effi-cient,controllable,and high-performance B-based fuel systems.Attached with 87 references.

段泽群;李明宇;张洋;曲文刚;杨磊;吕玺;庞维强

西安近代化学研究所含能材料全国重点实验室,陕西西安 710065西安近代化学研究所含能材料全国重点实验室,陕西西安 710065西安近代化学研究所含能材料全国重点实验室,陕西西安 710065西安近代化学研究所含能材料全国重点实验室,陕西西安 710065西安近代化学研究所含能材料全国重点实验室,陕西西安 710065陆军装备部驻西安地区军代局第十军代室,陕西西安 710025西安近代化学研究所含能材料全国重点实验室,陕西西安 710065

军事科技

物理化学金属氧化物金属氟化物表面改性点火性能金属燃料含能材料

physical chemistryboronmetal oxidesmetal fluoridessurface modificationignition performancemetal fuelenergetic materials

《火炸药学报》 2026 (4)

347-362,16

国家自然科学基金(No.22575186)

10.14077/j.issn.1007-7812.202512007

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