首页|期刊导航|环境工程学报|异相钙钛矿催化氧化技术在水处理中的研究进展

异相钙钛矿催化氧化技术在水处理中的研究进展OA

Advances in heterogeneous perovskite-based catalytic oxidation technologies for water treatment

中文摘要英文摘要

开发高效的非均相高级氧化技术是当前水处理领域的研究热点.其中,绿色高效的异相催化剂是关键.近年来,钙钛矿复合氧化物逐渐成为材料科学与催化领域的明星材料,凭借着其自身较高的晶格氧迁移速率、良好的电子迁移率、出色的热稳定性以及优异的氧化还原能力,使其在水污染修复领域中有着良好的研究价值和应用前景.该文综述了基于钙钛矿型氧化物的多种高级氧化技术,包括钙钛矿活化过氧化物(臭氧、过氧化氢和过硫酸盐),光、电、声、微波强化钙钛矿活化过氧化物等工艺,着重讨论了各自的应用场景、处理效能以及活性氧化物种的生成机制与氧化反应机理;总结了不同界面工程、结构调控手段对钙钛矿催化氧化性能的影响;并探讨了钙钛矿异相高级氧化技术处理有机废水的未来发展前景和挑战.

The advancement of heterogeneous advanced oxidation technologies(AOTs)represents a major focus in water treatment research,where the development of green and efficient heterogeneous catalysts is of central importance.In recent years,perovskite composite oxides have emerged as promising materials in materials science and catalysis.Due to their high lattice oxygen transfer rate,good electron mobility,outstanding thermal stability,and strong redox properties,perovskite oxides demonstrate significant research value and promising application prospects in water pollution remediation.This article reviews various perovskite-based AOTs,including their use as heterogeneous catalysts to activate different peroxide systems(e.g.,ozone,hydrogen peroxide,and persulfate),as well as peroxide activation enhanced by external energy such as light,electrochemical field,ultrasound,and microwave.In addition,the application scope,efficiency,and mechanisms governing the generation of reactive species generation and oxidation pathways are discussed in detail.The effects of interfacial engineering and structural modulation strategies on catalytic performance are also comprehensively summarized.Finally,the development prospects and current challenges of perovskite-based AOTs are further highlighted.

刘夫珍;李朕;蔡洁;刘雨冰;徐晶;张晖;徐银

黄冈师范学院化学化工学院,催化材料制备及应用湖北省重点实验室,黄冈 438000湖北大学资源环境学院,区域开发与环境响应湖北省重点实验室,武汉 430062湖北大学资源环境学院,区域开发与环境响应湖北省重点实验室,武汉 430062湖北大学资源环境学院,区域开发与环境响应湖北省重点实验室,武汉 430062武汉大学海绵城市建设水系统科学湖北省重点实验室,武汉 430079武汉大学环境科学与工程系,武汉 430079湖北大学资源环境学院,区域开发与环境响应湖北省重点实验室,武汉 430062

资源环境

高级氧化钙钛矿催化剂活化反应机理外源能量有机废水

advanced oxidationperovskitescatalyst activationreaction mechanismexternal energyorganic wastewater

《环境工程学报》 2026 (4)

1004-1019,16

国家自然科学青年基金资助项目(22006034)湖北省自然科学基金资助项目(2022CFB986)武汉大学海绵城市建设水系统科学湖北省重点实验室开放基金资助项目(2021-3)

10.12030/j.cjee.202508059

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