疏水改性煅烧硅藻土砂浆的制备及性能OA
Preparation and Performance of Hydrophobic-Modified Calcined Diatomite Mortar
为提高水泥基材料的防水抗渗性,本文提出了一种绿色疏水粉末的制备方法.以硬脂酸为改性剂,采用机械球磨法对煅烧硅藻土(CD)进行疏水改性,以接触角为主要评价指标优化工艺参数,成功制备出疏水性优异的改性煅烧硅藻土(SA-CD).利用X射线衍射仪(XRD)、傅里叶变换红外光谱仪(FTIR)和扫描电子显微镜(SEM)对SA-CD进行表征,系统研究了 SA-CD以不同掺量替代水泥对砂浆性能的影响.结果表明:在硬脂酸掺量3%(质量分数)、球磨时间30 min、转速500 r/min的工艺条件下,所制备的SA-CD接触角达到152°;随SA-CD掺量增加,砂浆接触角持续增大,毛细吸水系数显著下降;同时,砂浆流动度呈先上升后下降的趋势;当SA-CD掺量为6%(质量分数)时,砂浆28 d抗折强度和抗压强度分别提升了 8.81%和10.44%.微观分析表明,适量SA-CD可改善孔隙结构,提高致密性,从而增强砂浆的综合性能.
To enhance the waterproofing and impermeability of cement-based materials,this paper proposed a method for preparing green superhydrophobic powder.Using stearic acid as modifier,calcined diatomite(CD)underwent hydrophobic modification via mechanical ball milling.Process parameters were optimized with contact angle as the primary evaluation metric,successfully yielding modified calcined diatomite(SA-CD)with outstanding hydrophobic properties.The SA-CD was characterized using X-ray diffractometer(XRD),Fourier transform infrared spectrophotometer(FTIR),and scanning electron microscopy(SEM).The effects of substituting cement with SA-CD at different dosages on mortar properties were systematically investigated.Results indicate that under process conditions of 3%(mass fraction)stearic acid dosage,30 min ball milling time,and 500 r/min rotation speed,the prepared SA-CD shows a contact angle of 152°.As the SA-CD dosage increases,the mortar contact angle continuously rises while the capillary water absorption coefficient significantly decreases,simultaneously exhibiting a flow trend that initially increases before decreasing.At a 6%(mass fraction)SA-CD,the mortar's 28 d flexural strength and compressive strength improve by 8.81%and 10.44%,respectively.Microscopic analysis indicates that moderate SA-CD dosage improves pore structure and enhances density,thereby strengthening the mortar's overall performance.
王海皓;甘元初;侯庆振;陈振富;金丹;付新博
南华大学土木工程学院,衡阳 421001南华大学土木工程学院,衡阳 421001||高性能特种混凝土湖南省重点实验室,衡阳 421001山东高速路桥国际工程有限公司,济南 250013南华大学土木工程学院,衡阳 421001||高性能特种混凝土湖南省重点实验室,衡阳 421001南华大学土木工程学院,衡阳 421001||高性能特种混凝土湖南省重点实验室,衡阳 421001南华大学土木工程学院,衡阳 421001
建筑与水利
硬脂酸煅烧硅藻土接触角毛细吸水力学性能微观结构
stearic acidcalcined diatomitecontact anglecapillary water absorptionmechanical propertymicrostructure
《硅酸盐通报》 2026 (4)
1122-1131,10
国家自然科学基金面上项目(51678286)
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