首页|期刊导航|电源技术|磷酸铁锂/碳气凝胶复合正极制备及其储能机制研究

磷酸铁锂/碳气凝胶复合正极制备及其储能机制研究OA

Preparation of LiFePO4/carbon aerogel composite cathode and its energy storage mechanism

中文摘要英文摘要

聚焦于利用具有高比表面积与丰富孔隙结构的碳气凝胶与磷酸铁锂复合,以提升复合电极的电化学性能.重点考察了磷酸铁锂粒径与碳气凝胶比表面积这两个关键物理特性对复合材料性能的影响.实验表明:小粒径磷酸铁锂与大比表面积碳气凝胶所构建的复合电极展现出优异的综合性能,其首次放电比容量高达165.5 mAh/g,首次库仑效率达到100.0%,且在500次循环后容量保持率仍高达94.6%.实验结果明确验证了原材料物理特性对复合材料电化学性能的显著影响,为后续设计高性能磷酸铁锂/碳气凝胶复合电极提供了重要的优化依据.

To enhance electrochemical performance,LiFePO4(LFP)was composited with carbon aero-gel(CA),leveraging its high specific surface area and porous structure.This work specifically investi-gates the effects of two key physical properties—LFP particle size and CA's specific surface area—on the composite's performance.Experiments demonstrate that the composite electrode constructed with small-sized LFP and high-specific-surface-area CA exhibits excellent comprehensive perfor-mance,delivering an initial discharge specific capacity of up to 165.5 mAh/g with an initial Coulom-bic efficiency of 100.0%,and maintaining a high capacity retention rate of 94.6%after 500 cycles.This result clearly verifies the significant impact of raw materials'physical properties on the electro-chemical performance of the composite and provides an important optimization basis for the subse-quent design of high-performance LFP/CA composite electrodes.

尤露媛;张舒茜;乔志军;于学文;阮殿波

宁波大学机械工程与力学学院,浙江 宁波 315211||全省特种电化学储能电源重点实验室,浙江 宁波 315211宁波大学机械工程与力学学院,浙江 宁波 315211||全省特种电化学储能电源重点实验室,浙江 宁波 315211宁波大学机械工程与力学学院,浙江 宁波 315211||全省特种电化学储能电源重点实验室,浙江 宁波 315211宁波工程学院新能源学院,浙江 宁波 315112宁波大学机械工程与力学学院,浙江 宁波 315211||全省特种电化学储能电源重点实验室,浙江 宁波 315211

信息技术与安全科学

磷酸铁锂碳气凝胶复合正极耦合协同储能物理参数调控

LiFePO4carbon aerogelcomposite materialsynergistic effectspecific surface area

《电源技术》 2026 (5)

810-817,8

10.3969/j.issn.1002-087X.2026.05.004

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