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煤岩体对矿井水常规阳离子演化规律的影响OA

Impact of coal-rock interactions on the geochemical evolution of major cations in mine water

中文摘要英文摘要

以平顶山矿区的煤与矸石为研究对象,探究了不同粒径、溶液环境等条件下常规阳离子的释放规律,并阐明了释放行为对矿井水矿化特征的影响机制.结果表明:煤与矸石的粒径对离子释放量和浸泡液pH值具有显著影响.粒径减小,煤岩体中铝硅酸盐、碳酸盐类矿物质的水解反应增强,Si4+、Al3+等主要离子的释放量增加;矸石主要贡献Si4+和Al3+,煤主要贡献Ca2+,且矸石的存在会抑制Ca2+的释放;在矿井水作用下,煤和矸石的离子释放规律与去离子水环境存在差异,矿井水中的Ca2+和Mg2+质量浓度主要受煤的影响.研究表明,煤与矸石的协同作用显著影响矿井水的化学性质,初始溶液环境主要调控离子释放和pH值的动态变化过程.

This study investigates the release patterns of major cations from coal and gangue collected from the Pingdingshan mining area under various conditions,including particle size and solution chemistry,with the aim of elucidating the underlying mechanisms controlling mine water mineralization.Laboratory experiments were conducted to analyze ion release characteristics and pH evolution.The results show that particle size plays a critical role in controlling ion release and solution pH.Finer particles enhance the dissolution of aluminosilicates and carbonate materials in coal-bearing strata,leading to enhanced release of key ions such as Si4+and Al3+.Gangue is identified as the primary source of Si4+and Al3+,whereas coal predominantly contributes Ca2+;moreover,the presence of gangue suppresses the release of Ca2+.Ion release patterns in actual mine water differ from those observed in deionized water,with Ca2+and Mg2+concentrations in mine water mainly governed by coal.Overall,the findings demonstrate that the interactions between coal and gangue significantly impacts the geochemical evolution of mine water,while the initial solution environment primarily regulates the dynamics of ion release and pH changes.

路凯旋;罗庆;罗洁;徐连满

沈阳大学 区域污染环境生态修复教育部重点实验室,沈阳 110044||中国刑事警察学院 公安信息技术与情报学院,沈阳 110854沈阳大学 区域污染环境生态修复教育部重点实验室,沈阳 110044辽宁大学 环境学院,沈阳 110036辽宁大学 环境学院,沈阳 110036

资源环境

矿井水煤与矸石常规离子水质演化

mine watercoal and ganguemajor cationswater quality evolution

《重庆大学学报》 2026 (6)

14-23,10

国家重点研发计划资助(2024YFC3013904)深地工程智能建造与健康运维全国重点实验室开放基金课题(SDGZ2527)兴辽英才计划(XLYC2203141).Supported by National Key R&D Program of China(2024YFC3013904),State Key Laboratory of Intelligent Construction and Healthy Operation and Maintenance of Deep Underground Engineering(SDGZ2527),and Liaoning Revitalization Talents Program(XLYC2203141).

10.11835/j.issn.1000-582X.2025.282

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