首页|期刊导航|广州化学|钐掺杂镍钴双金属氢氧化物/碳布复合材料的制备及电化学性能

钐掺杂镍钴双金属氢氧化物/碳布复合材料的制备及电化学性能OA

Preparation and Electrochemical Properties of Samarium-Doped Nickel-Cobalt Bimetallic Hydroxide/Carbon Cloth Composites

中文摘要英文摘要

以六水合硝酸镍为镍源、六水合硝酸钴为钴源,以六水合硝酸钐为掺杂剂,采用一步水热法在活性碳布上负载钐掺杂的镍钴双金属氢氧化物,采用XRD、SEM、TEM、XPS、BET对复合电极进行物相表征.得到的钐掺杂镍钴双金属氢氧化物为非晶态的毛刺状一维纳米结构,均匀致密地阵列式垂直排布于碳布表面.该复合材料比表面积为78.199 m2/g,孔径为3.046 nm.电化学性能测试结果显示,该复合材料在1 A/g的电流密度下比电容为4498.2 F/g,循环1000次后比电容保持率为92.23%.本研究为氢氧化物基高性能电极材料开发提供了新的思路,为制备Sm掺杂高性能复合电极提供了简单的方法.

The samarium-doped nickel-cobalt bimetallic hydroxide was loaded on the activated carbon cloth by one-step hydrothermal method using nickel nitrate hexahydrate as the nickel source,cobalt nitrate hexahydrate as the cobalt source,and samarium nitrate hexahydrate as the dopant,and the composite electrode was characterized by XRD,SEM,TEM,XPS,and BET for the physical phase.The obtained samarium-doped nickel-cobalt bimetallic hydroxide is an amorphous burr-like one-dimensional nanostructure,which is uniformly and densely arrayed vertically on the surface of the carbon cloth.The specific surface area of the composite was 78.199 m2/g,and the pore size was 3.046 nm.Electrochemical performance tests showed that the specific capacitance of the composite was 4498.2 F/g at a current density of 1 A/g,and the retention of the specific capacitance was 92.23%after 1000 cycles.This study provides a new idea for the development of hydroxide-based high-performance electrode materials and a simple method for the preparation of Sm-doped high-performance composite electrodes.

高宇;任玲玲;冯青青;邢东风;陈娇;金达莱

浙江理工大学材料科学与工程学院,浙江 杭州 310018浙江省现代纺织技术创新中心,浙江绍兴 312000浙江省现代纺织技术创新中心,浙江绍兴 312000浙江省现代纺织技术创新中心,浙江绍兴 312000浙江理工大学材料科学与工程学院,浙江 杭州 310018浙江理工大学材料科学与工程学院,浙江 杭州 310018

信息技术与安全科学

超级电容器电极镍钴双金属氢氧化物纳米阵列钐掺杂

supercapacitor electrodenickel-cobalt bimetallic hydroxidenanoarraysamarium doping

《广州化学》 2026 (2)

9-14,6

浙江省重点研发项目(2023C01095)

10.16560/j.cnki.gzhx.20252648

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