首页|期刊导航|钢铁钒钛|TiC-NbC协同强化铁基合金耐磨涂层的微观组织与力学性能研究综述

TiC-NbC协同强化铁基合金耐磨涂层的微观组织与力学性能研究综述OA

Review on the microstructure and mechanical properties of TiC-NbC synergistically strengthened iron-based alloy wear-resistant coatings

中文摘要英文摘要

在高温、重载、高速摩擦等极端工况下,采用先进的表面工程技术在钢铁基体表面制备铁基耐磨涂层是延长关键部件服役寿命、实现资源循环利用的有效途径.传统Fe-Cr-C合金中常形成粗大的M7C3型初生碳化物,这些脆性相易在苛刻服役环境下成为裂纹源,影响涂层使用寿命.引入Nb元素可在晶界析出尺寸细小的NbC,从而抑制裂纹萌生并降低开裂倾向.然而,过量添加Nb会导致NbC偏聚并形成粗大颗粒,不利于提升涂层性能.进一步引入Ti元素能够与C原位反应形成稳定且高硬度的TiC,并作为NbC的异质形核核心,从而实现组织的细化与均匀化,有效改善涂层的综合性能.文章综述了原位生成TiC与NbC协同作用的形核机制及Fe-Cr-C合金涂层中引入Nb、Ti元素对涂层显微组织和力学性能的影响,为高性能耐磨铁基合金涂层的应用研究提供理论支撑.

Under extreme operating conditions such as high temperature,heavy load,and high-speed friction,applying advanced surface engineering technologies to fabricate iron-based wear-resistant coat-ings on steel substrates is an effective approach to extend the service life of critical components and pro-mote resource recycling.In conventional Fe-Cr-C alloys,coarse primary M7C3-type carbides often form;these brittle phases can readily become crack initiation sites under severe service conditions,comprom-ising the coating's durability.The addition of Nb can lead to the precipitation of fine NbC particles at grain boundaries,thereby suppressing crack initiation and reducing the propensity for cracking.However,excessive Nb addition may cause NbC to agglomerate and form coarse particles,which is det-rimental to coating performance.Further introduction of Ti enables in-situ reactions with C to form stable and high-hardness TiC,which can act as heterogeneous nucleation sites for NbC,thus refining and homogenizing the microstructure and effectively enhancing the overall properties of the coating.This review summarizes the nucleation mechanisms involving the synergistic effect of in-situ formed TiC and NbC,and discusses the influence of Nb and Ti additions on the microstructure and mechanical properties of Fe-Cr-C-based alloy coatings,providing theoretical support for the applied research of high-performance wear-resistant iron-based alloy coatings.

绍瑞;李子逸;冯中学;陈敏;刘许旸;翁刘;张雪峰

昆明理工大学材料科学与工程学院,云南 昆明 650093昆明理工大学材料科学与工程学院,云南 昆明 650093昆明理工大学材料科学与工程学院,云南 昆明 650093||四川钒钛产业技术研究院,四川攀枝花 617000四川钒钛产业技术研究院,四川攀枝花 617000||攀枝花学院钛钒学院,四川攀枝花 617000重庆大学航空航天工程学院,重庆 400044攀枝花学院钛钒学院,四川攀枝花 617000四川钒钛产业技术研究院,四川攀枝花 617000

矿业与冶金

碳钢铁基合金耐磨涂层TiCNbC显微组织力学性能

steeliron-based alloys coatingTiCNbCmicrostructuremechanical properties

《钢铁钒钛》 2026 (1)

49-61,13

四川省中央引导地方科技发展专项(2024ZYD0330)贵州省教育厅"百校千企科技攻关揭榜挂帅"项目(贵州教育科技[2024]No.003)云南省重大科技项目(202202AG050011)中央对地方科技发展基金项目的指导(2024ZYD0330)攀枝花市省级定向财政转移支付项目(22ZYZF-G-02,21ZYZF-G-01).

10.7513/j.issn.1004-7638.2026.01.006

评论