冷却温度-保温时间对熔分钛渣析晶的影响OA
Effect of cooling temperature-holding time on the crystallization of molten-separated titanium slag
以某钢厂熔分钛渣为研究对象,通过高温熔析试验并结合XRD分析,系统探究了冷却温度(1 150~1 300 ℃)协同保温时间(0~60 min)对熔分钛渣析晶行为的影响规律.结果表明:黑钛石相-MgTi2O5最优析晶窗口为温度1 250~1 300℃,时间30~50 min,析出量达51.2%~56.2%;假板钛矿-Fe2TiO5最优析晶窗口为温度1 150~1 200 ℃,时间40~60 min,析出量达38%~40%;金红石-TiO2最优析晶窗口为温度1 150~1 200 ℃,时间0~30 min,析出量25%~35%.三者析晶行为呈现明显竞争关系,且单一物相优势析晶区间与其余两相抑制区高度重叠,为熔分钛渣特定含钛物相析晶的定向促进或靶向抑制提供精准工艺优化窗口,为工业熔分钛渣钛组分定向分离与提取提供了理论依据.
To achieve efficient extraction of titanium components from molten-separated titanium slag,this study took the slag from a steel plant as the research object,and systematically investigated the crystallization behavior of the slag under synergistic control of cooling temperature(1150~1300 ℃)and holding time(0~60 min)through high-temperature melting crystallization experiment and XRD analys-is.The results indicated that the optimal crystallization window for anosovite-MgTi2O5 is 1250~1300 ℃ with 30~50 min,and the precipitation amount reaches 51.2%~56.2%;the optimal crystallization win-dow for pseudobrookite-Fe2TiO5 is 1150~1200 ℃ with 40~60 min,and the precipitation amount is 38%~40%;the optimal crystallization window for rutile-TiO2 is 1150~1200℃ with 0~30 min,and the precipitation amount reaches 25%~35%.The crystallization behaviors of the three phases exhibit an ob-vious competitive relationship,and the optimal crystallization window of a single phase highly overlaps with the suppression regions of the other two.This provides a precise process optimization window for either directional promotion or targeted suppression of specific titanium-bearing phases,offering a the-oretical basis for the directional separation and extraction of titanium components from industrial mol-ten-separated titanium slag.
李晨辉;杜培培;赵素兴;田铁磊;李兰杰;龙跃
华北理工大学冶金与能源学院,河北唐山 063210华北理工大学冶金与能源学院,河北唐山 063210河钢材料技术研究院,河北石家庄 050023华北理工大学冶金与能源学院,河北唐山 063210河钢材料技术研究院,河北石家庄 050023华北理工大学冶金与能源学院,河北唐山 063210
矿业与冶金
熔分钛渣冷却温度保温时间析晶行为
molten-separated titanium slagcooling temperatureholding timecrystallization behavior
《钢铁钒钛》 2026 (1)
17-27,11
国家重点研发计划重点专项(2024YFC3909503)河北省重大科技成果转化专项(23284101Z)河钢集团重点科技项目(HG2023209).
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