首页|期刊导航|分析测试学报|基于顶空气相色谱-离子迁移谱的掌叶覆盆子不同部位挥发性成分分析

基于顶空气相色谱-离子迁移谱的掌叶覆盆子不同部位挥发性成分分析OA

Analysis of Volatile Components in Different Parts of Rubus chingii Hu Based on Headspace Gas Chromatography Ion Mobility Spectrometry

中文摘要英文摘要

采用顶空气相色谱-离子迁移谱(HS-GC-IMS)测定了掌叶覆盆子6个部位(根、果、嫩叶、老叶、嫩茎和老茎)样品中的挥发性成分,运用VOCal软件对挥发性成分进行定性分析,建立了GC-IMS指纹图谱.结合主成分分析、偏最小二乘判别分析和聚类热图,研究各部位间的挥发性成分差异.结果显示,从6个部位中共检出128种挥发性成分,鉴别出92种,包括醇类23种、醛类28种、酮类13种、酯类8种等;GC-IMS指纹图谱显示,6个不同部位中挥发性成分相似,但含量差异显著.基于VIP>1.2筛选出(E)-2-己烯醛-D、乙酸甲酯、3-甲基丁醇-D等17种差异挥发性成分,可作为各部位的特征成分,为实现掌叶覆盆子不同部位挥发性成分的快速、准确鉴别提供了新方法.

The volatile components in different parts(root,fruit,leaflet,old leaf,tender stem and old stem)of Rubus chingii Hu(R.chingii)were determined by headspace gas chromatography ion mo‑bility spectrometry(HS-GC-IMS).By focusing on the differences of volatile components in six differ‑ent parts of R.chingii,combined with principal component analysis,partial least squares discrimi‑nant analysis and cluster heat map,the differences of volatile components in different parts were stud‑ied.The results showed that a total of 128 volatile components were obtained from six different parts,92 of which were identified,including 23 alcohols,28 aldehydes,13 ketones,and 8 esters,etc.;GC-IMS fingerprints showed that the volatile components in six different parts were similar,but the content difference was obvious.According to VIP>1.2,17 different components such as(E)-2-hexe‑nal-D,methyl acetate and 3-methylbutanol-D were screened out.The differences of volatile compo‑nents in different parts of R.chingii were analyzed,which provided a new method for rapid and accu‑rate identification of volatile components in different parts of R.chingii.

李静;于强;杨敏;潘萍;陈菲;陈宏降;罗益远

浙江海洋大学 食品与药学学院,浙江 舟山 316022浙江海洋大学 食品与药学学院,浙江 舟山 316022浙江海洋大学 食品与药学学院,浙江 舟山 316022浙江药科职业大学 中药学院,浙江 宁波 315500||宁波市中药资源综合开发利用重点实验室,浙江 宁波 315500如皋市中医院 药剂科,江苏 如皋 226500浙江药科职业大学 中药学院,浙江 宁波 315500||宁波市中药资源综合开发利用重点实验室,浙江 宁波 315500浙江药科职业大学 中药学院,浙江 宁波 315500||宁波市中药资源综合开发利用重点实验室,浙江 宁波 315500

化学化工

掌叶覆盆子顶空气相色谱-离子迁移谱不同部位挥发性成分

Rubus chingii HuHS-GC-IMSdifferent partsvolatile components

《分析测试学报》 2026 (5)

1001-1010,10

宁波市公益计划项目(2025S150)浙江省药品监督管理局科技计划项目(2025031)浙江省教育厅科研项目(Y202557366)南通市卫生健康委科研课题(QNZ2024094)江苏省药学会—"药"研新声药学科研项目课题(202495038)如皋市科技攻关计划(农业和社会发展)项目(SRGS(24)013)

10.12452/j.fxcsxb.26010602

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