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茶叶中的铷(Rb)含量研究OA

Study on the Content of Rubidium in Tea

中文摘要英文摘要

[目的]基于目前茶叶矿质元素中涉铷(Rb)元素研究的不足,对茶叶中的 Rb含量进行测定分析,以充分了解茶叶涉 Rb元素的相关性能,为茶叶矿质元素研究提供新视角.[方法]采用国家标准,测定 36个茶叶样品中总灰分、水不溶灰分,采用能量色散X荧光光谱法(Energy Dispersive X-ray Fluorescence Spectroscopy,EDXRF法)测定样品总灰分、水不溶灰分中的 Rb含量,计算出样品中 Rb元素溶出率及含量、10 g·d-1 饮用茶计Rb摄入量值,并分析 EDXRF谱图中包括 Rb元素在内的具特征峰元素的谱图特性.[结果]36个不同茶叶样品总灰分 EDXRF谱图的所有元素特征峰中,Rb元素特征峰居第 1、2、3高峰的样品分别占样品总数的30.6%、27.8%、30.6%,基于 EDXRF法检测技术筛选原理,应将 Rb元素列为茶叶主要矿质元素进行研究.36个茶叶样品的 Rb元素溶出率为 87.83%~99.90%,Rb元素含量为 18.85~417.24 mg·kg-1,其中按茶类归类的类群分析中高 Rb含量类群与中低类群的 Rb含量存在显著性差异,按地理产区归类的类群分析中高、中、低 Rb含量类群之间的 Rb含量存在显著性差异;10 g·d-1 饮用茶计 Rb摄入量为 0.18~4.07 mg·d-1.[结论]不同茶叶总灰分 EDXRF谱图中均具有显著 Rb元素特征峰,显示 Rb元素应为茶叶微量元素研究中主要元素之一.不同茶类和地理产区茶叶 Rb元素含量相差较大,但均具高溶出率的特点.结合目前茶叶涉 Rb元素研究重视不足的现状,建议加强茶叶涉Rb元素研究.

[Objective]Analysis of rubidium(Rb)in tea was conducted to provide information currently lacking for research and technical needs.[Method]Dry matter,total ash,and water-insoluble ash in 36 tea specimens were determined by the national standard analytical methods.Rb in the ash was measured using energy dispersive X-ray fluorescence spectroscopy(EDXRF)with peaks in the spectrum analyzed.Solubility of Rb in tea were determined,and dietary intake from 10 g·d-1 of tea drinking calculated.[Result]The 36 tea specimens that showed three top EDXRF peaks to be Rb amounted to significant 30.6%,27.8%,and 30.6%of all.Hence,Rb ought to be viewed as an important mineral in studying teas.The extraction rates of Rb in the sampled teas ranged from 87.83%to 99.90%with a content between 18.85 mg·kg-1 and 417.24 mg·kg-1.The difference between the medium-high and medium-low Rb contents of the teas was significant.Those among the medium-high,medium,and low contents in the teas of same geographic origin were significant as well.Based on daily consumption of 10 g,the Rb intakes from the variety teas were estimated to be 0.18-4.07 mg·d-1.[Conclusion]The 36 varieties of teas showed significant Rb peaks on EDXRF spectrum indicating a deserved attention of the trace element in studying teas.The generally highly soluble Rb varied significantly in content by tea types and of different production areas.

吴盛祺;杜文佳;赖晓锋;刘春梅;扈廷勇

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农业科技

茶叶Rb元素能量色散X荧光光谱法溶出率摄入量

TeaRbenergy dispersive X-ray fluorescence spectroscopyextraction ratedietary intake

《茶叶学报》 2026 (1)

59-69,11

中央引导地方科技发展资金项目(202301003).

10.20045/j.cnki.issn.2096-0220.2026.01.006

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