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负载相变微胶囊的纸基复合材料降温性能研究OA

Study on the Cooling Performance of Paper-based Composites Containing Phase Change Microcapsules

中文摘要英文摘要

本研究以纸为基材,利用聚乙烯醇(PVA)溶液分散相变微胶囊(PCM)制备涂布液,将其涂布在纸上制备负载相变微胶囊的纸基复合材料(C-PCM),用于加热不燃烧卷烟(HNB)降温段.并优化了PVA质量分数、相变温度及涂布工艺对C-PCM性能的影响.结果表明,涂布液最佳制备条件为 PVA 质量分数 5%,PCM 相变温度 45℃,涂布液固含量 20%,此条件下制备的C-PCM可将滤嘴最高温度降至37.4℃,降温效果显著优于国外市售产品.此外,C-PCM还具备良好的抗张指数(57.4 N·m/g)、亲水性(水接触角44.2°)和防油性,综合性能满足HNB卷烟的实际需求.在尽量保持复合材料降温性能的同时,添加适量的CaCO3填料可以替代相变微胶囊以节约成本.

In this study,a novel paper-based composites containing phase change microcapsules(C-PCM)was fabricated for the cooling segment of heat not burn(HNB)cigarettes.Using paper as the substrate,a coating solution was prepared by dispersing phase change mi-crocapsules(PCM)in a polyvinyl alcohol(PVA)solution,which was then applied onto the paper.Through optimization of PVA concentra-tion,phase change temperature,and coating parameters,the coating solution optimal preparation conditions were determined as:PVA solu-tion mass fraction was 5%,PCM phase change temperature was 45℃,coating solution solid content was 20%.The C-PCM prepared under this condition reduced the maximum temperature of the cigarette filter to 37.4℃,significantly outperforming commercially available HNB cigarette filters.The phase change enthalpy of C-PCM reached 120.3 J/g at this coating condition,confirming excellent heat absorption ca-pability.Additionally,C-PCM exhibits favorable tensile index(57.4 N·m/g),hydrophilicity(water contact angle 44.2°),and oil resistance.When maintaining the cooling performance of C-PCM as much as possible,adding an appropriate amount of CaCO3 thermal conductive fill-er could replace an appropriate amount of phase change microcapsules to save costs.

张莹;赵丽君;朝鲁门;杨扬;黄剑波;李鸿凯;刘文;王嵩鹏

造纸工业生产力促进中心,浙江 衢州,324400||吉林师范大学化学学院,吉林四平,136000造纸工业生产力促进中心,浙江 衢州,324400中国制浆造纸研究院有限公司,北京,100102中国制浆造纸研究院有限公司,北京,100102中国制浆造纸研究院有限公司,北京,100102造纸工业生产力促进中心,浙江 衢州,324400造纸工业生产力促进中心,浙江 衢州,324400||中国制浆造纸研究院有限公司,北京,100102造纸工业生产力促进中心,浙江 衢州,324400

轻工纺织

纸基复合材料相变微胶囊涂布降温效果

paper-based compositesphase change microcapsule(PCM)coatingcooling effect

《中国造纸》 2026 (4)

51-55,179,6

制浆造纸国家工程实验室基金项目(ZZY2023ZZXT02).

10.11980/j.issn.0254-508X.2026.04.007

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