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硬质聚氨酯泡沫无卤阻燃体系的研究进展OA

Research progress on halogen-free flame retardant systems for rigid polyurethane foam

中文摘要英文摘要

硬质聚氨酯泡沫(RPUF)作为一种性能良好的保温材料,常常应用于建筑、制冷、管路运输等,但其易燃性也带来极大的安全隐患.传统的卤系阻燃材料虽然能大幅改善其阻燃性能,但也会对环境产生较大的危害,因此开发无卤阻燃体系变得尤为重要.本文综述了近年来用于硬质聚氨酯泡沫阻燃改性的无卤阻燃体系的研究进展,包括无机阻燃剂、有机磷系阻燃剂以及其他无卤阻燃剂,重点介绍了这三类阻燃剂对于RPUF阻燃性的影响.最后讨论了近年来新型材料在RPUF阻燃改性上的应用,以及未来研究的可能.

Rigid polyurethane foam(RPUF),as a type of high-performance thermal insulation material,is widely used in construction,refrigeration,pipeline transportation,and other fields.However,its flammability presents a significant safety hazard.Although conventional halogenated flame retardants can effectively enhance its flame retardancy,they also pose serious environmental risks.Therefore,the development of halogen-free flame retardant systems has become partic-ularly crucial.This article reviews recent research progress in halogen-free flame retardant systems for the flame retar-dant modification of rigid polyurethane foam.These systems include inorganic flame retardants,organic phosphorus-based flame retardants,and other halogen-free alternatives,with a focus on the effects of these three types of flame retar-dants on the flame retardancy of RPUF.Finally,the article discusses the application of novel materials in RPUF flame retardant modification in recent years and outlines potential future research directions.

李贺;高大海;方兵;闫宝林;于建香;戴玉华

北京石油化工学院新材料与化工学院,特种弹性体复合材料北京市重点实验室,北京 102617北京石油化工学院新材料与化工学院,特种弹性体复合材料北京市重点实验室,北京 102617北京石油化工学院新材料与化工学院,特种弹性体复合材料北京市重点实验室,北京 102617北京石油化工学院新材料与化工学院,特种弹性体复合材料北京市重点实验室,北京 102617北京石油化工学院新材料与化工学院,特种弹性体复合材料北京市重点实验室,北京 102617北京石油化工学院新材料与化工学院,特种弹性体复合材料北京市重点实验室,北京 102617

化学化工

硬质聚氨酯泡沫无机阻燃剂有机磷系阻燃剂无卤阻燃剂

rigid polyurethane foaminorganic flame retardantsorganophosphorus flame retardantshalogen-free flame retardants

《中国塑料》 2026 (4)

137-148,12

10.19491/j.issn.1001-9278.2026.04.021

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