生物炭与水热炭的表征及应用研究进展OA
Recent advances in the characterization and applications of biochar and hydrochar
将生物质转化为富炭材料、生物炭与水热炭,已成为应对严峻环境挑战、支撑可持续工业发展的重要途径.本文全面分析了这类材料在表征与应用方面的最新进展,重点阐述了其不同制备方法、理化性质及功能多样性.生物炭通常由高温热解制得,具有高孔隙率、芳香性和热稳定性,适用于CO2 捕集、电化学储能、催化及土壤改良等领域.与之相对,水热炭在温和温度下通过水热炭化在水介质中制备,保留了更多表面官能团与杂原子,在水相催化、污染物吸附和生物修复中更具优势.本文概述了理化表征对优化材料性能的关键作用,通过液氮吸附、扫描电镜、X射线衍射仪、X射线光电子能谱仪、拉曼光谱仪、红外光谱仪,Boehm滴定和热重分析等技术,阐明了比表面积、官能团化学、石墨化程度等理化特性决定材料在特定场景下的适用性.还探讨了这些材料在废水处理、生物燃料生产、动物饲料以及高级氧化工艺等方面的新应用,并分析了其与联合国多项可持续发展目标(尤其是气候行动、清洁能源和负责任生产方面)的相关性.这些材料用途广泛,可大规模生产.这类材料多功能性强、可规模化制备,性能可通过不同制备与后处理工艺精细调控,是向循环低碳经济转型的关键支撑材料.
The conversion of biomass into carbon-rich materials,biochar and hydrochar,has emerged as a promising strategy to solve pressing environmental challenges while supporting sustainable industrial de-velopment.A comprehensive analysis of recent ad-vances in the characterization and application of these materials,is provided,emphasizing their distinct pro-duction methods,physicochemical properties,and functional versatility.Biochar,typically obtained by pyrolysis at high temperatures,has a high porosity,aromaticity,and thermal stability,making it well-suited for applications such as CO2 capture,electro-chemical energy storage,catalysis,and soil improve-ment.In contrast,hydrochar,produced by hydro-thermal carbonization in aqueous media at moderate temperatures,retains a higher number of surface functional groups and heteroatoms,offering advant-ages in aqueous-phase catalysis,pollutant adsorption,and bioremediation.The critical role of physicochem-ical characterization in optimizing material perform-ance is outlined,and analytical techniques including liquid nitrogen adsorption,scanning electron microscopy,X-ray diffrac-tion,X-ray photoelectron spectroscopy,Raman spectroscopy,infrared spectroscopy,Boehm titration,and thermogravimetric analysis are discussed.These show how physical-chemical characteristics such as surface area,functional group chemistry,and degree of graphitization,govern the materials'suitability for specific applications.Emerging uses in waste water treatment,bio-fuel production,animal feed,and advanced oxidation processes are examined,alongside their relevance to multiple UN Sustain-able Development Goals,particularly in climate action,clean energy,and responsible production.The materials are versatile and can be produced on a large scale.Their performance can be fine-tuned using different production and post-treatment pro-cesses,making them key enablers in the transition to a circular,carbon-conscious economy.
Bruna Rijo;Ana Paula Soares Dias
VALORIZA—Research Centre for Endogenous Resource Valorization,Polytechnic Institute of Portalegre,7300-555,Portalegre,PortugalVALORIZA—Research Centre for Endogenous Resource Valorization,Polytechnic Institute of Portalegre,7300-555,Portalegre,Portugal||CERENA,Institute Superior Técnico,University de Lisboa,1049-001,Lisbon,Portugal
化学化工
生物炭水热炭特性分析官能团可持续应用
BiocharHydrocharCharacterizationFunctional groupsSustainable applications
《新型炭材料(中英文)》 2026 (2)
276-298,23
The authors gratefully acknowledge the support of the CERENA(FCT-UIDB/04028/2025 and FCT-UIDP/04028/2025)and VALORIZA-Research Centre for Endogenous Resource Valorization(FCT-UID/05064/2025).
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