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丙烯氧酰化合成醋酸烯丙酯催化剂研究进展OA

Research progress on catalysts for allyl acetate synthesis via propylene oxyacetylation

中文摘要英文摘要

醋酸烯丙酯(AAc)是一种重要的有机化工原料,其下游衍生物在多领域应用广泛.丙烯氧酰化是合成醋酸烯丙酯的重要途径,而催化剂是影响该过程的核心.对醋酸烯丙酯催化剂(主要是Pd-Cu催化剂)的研究进展进行了综述,首先介绍了催化合成AAc的两种主要反应机理,然后总结了载体改性、活性组分优化、助催化剂筛选及制备工艺改进对催化剂催化性能的影响,最后对醋酸烯丙酯催化剂的未来研究方向进行了展望.

Allyl acetate(AAc)is an important organic chemical feedstock,and its downstream derivatives find extensive application in multiple fields.Allyl oxylation is an important approach for the synthesis of allyl acetate,and the catalyst is the core factor influencing this process.The research progress on allyl acetate catalysts(mainly Pd-Cu catalysts)was reviewed.Firstly,two main reaction mechanisms for the catalytic synthesis of AAc were introduced.Then,the effects of support modification,optimization of active components,screening of co-catalysts and improvement of preparation processes on the catalytic performances of the catalysts were summarized.Finally,the future research directions of allyl acetate catalysts were prospected.

张荣凡;孙浩洋;邱鹏远;刘军晓;张丽斌;杨运信

中石化(上海)石油化工研究院有限公司 上海 201208中石化(上海)石油化工研究院有限公司 上海 201208中石化(上海)石油化工研究院有限公司 上海 201208中石化(上海)石油化工研究院有限公司 上海 201208中石化(上海)石油化工研究院有限公司 上海 201208中石化(上海)石油化工研究院有限公司 上海 201208

化学化工

醋酸烯丙酯丙烯氧酰化Pd-Cu催化剂

allyll acetatepropyleneoxyacetylationPd-Cu catalysts

《低碳化学与化工》 2026 (4)

49-58,69,11

中国石油化工股份有限公司资助项目(224062).

10.12434/j.issn.2097-2547.20250221

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