铁碳填料的曝气生物滤池处理海水养殖废水的效能与机制OA
Studies on the Efficacy and Mechanism of Aerated Biofilter with Iron-Carbon Packing for the Treatment of Mariculture Wastewater
针对传统生物处理方法处理海水养殖废水效果不佳的现状,本研究构建了以铁碳(Iron-carbon,FeC)为填料的曝气生物滤池(Biological aerated filter,BAF)系统,分析了FeC填料的静态吸附特性,研究了不同水力停留时间和气水比条件下FeC填料的BAF对海水养殖废水的脱氮除磷效果,并深入探讨了其作用机制.研究表明,与活性炭(Granular active carbon,GAC)、陶粒相比,FeC填料表现出更好的静态磷酸盐吸附性能,通过吸附动力学和吸附等温线拟合,得到FeC填料的最大磷酸盐吸附容量分别为1.80和1.69 mg·g-1.工艺运行条件优化结果表明,最佳水力停留时间为9 h,此时总氮(Total nitrogen,TN)和总磷(Total phosphorus,TP)去除率分别达到58.00%和93.65%;最佳气水比为5∶1,此时TN和TP去除率分别达到60.43%和93.64%.对使用前后的FeC填料进行X射线衍射表征,发现FeC填料释放的铁离子和其他金属离子与磷酸盐形成共沉淀是除磷的关键机制.同时对比陶粒BAF和铁碳BAF系统中门水平微生物群落结构,发现FeC填料能够促进系统中脱氮除磷相关功能细菌的富集.
To solve the problem of poor effect of traditional biological treatment methods in treating mariculture tail water,a biological aerated filter(BAF)system was constructed with iron and carbon materials as fillers,the static pollutant adsorption characteristics of iron and carbon fillers were analyzed,and the effects of the system on nitrogen and phosphorus removal from mariculture wastewater with different hydraulic retention times and gas-to-water ratios were compared,and the mechanism of the system was explored.The results showed that compared with granular activated carbon(GAC)and ceramic FeC packing showed better static phosphate adsorption performance.The maximum phosphate adsorption capacity of FeC packing obtained from adsorption kinetic fitting and adsorption isotherm fitting was 1.80 and 1.69 mg·g-1,respectively.The optimal hydraulic retention time was 9 h,corresponding to the total nitrogen(TN)and total phosphorus(TP)removal rate of 58.00%and 93.65%.The optimal gas-to-water ratio was 5∶1,corresponding to the TN and TP removal rate of 60.43%and 93.64%.The X-ray diffraction characterization of the FeC filler before and after use showed that the co-precipitation of iron ions and other metal ions released by FeC filler with phosphate was the key mechanism for phosphorus removal.Comparison of the microbial community structure at the phylum level in ceramic BAF and iron-carbon BAF systems showed that FeC filler may promote the enrichment of functional bacteria related to denitrification and phosphorus removal in the system.
徐溢波;相壮壮;李辉;白洁;陈晓红;孙惠琛;晨曦
中国海洋大学环境科学与工程学院,山东 青岛 266100中国海洋大学环境科学与工程学院,山东 青岛 266100中国海洋大学环境科学与工程学院,山东 青岛 266100||中国海洋大学海洋环境与生态教育部重点实验室,山东 青岛 266100中国海洋大学环境科学与工程学院,山东 青岛 266100||中国海洋大学海洋环境与生态教育部重点实验室,山东 青岛 266100威海汇海海洋科技有限公司,山东 威海 264400中国海洋大学环境科学与工程学院,山东 青岛 266100中国海洋大学海洋生命学院,山东 青岛 266003
农业科技
铁碳填料曝气生物滤池海水养殖废水脱氮除磷微生物群落
iron-carbon packingbiological aerated filtermariculture wastewaternitrogen and phos-phorus removalmicrobial community
《中国海洋大学学报(自然科学版)》 2026 (5)
120-128,9
国家自然科学基金项目(U20A20103)资助 Supported by the National Natural Science Foundation of China(U20A20103)
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