片状羰基铁聚酯纤维增强复合材料制备及吸波性能研究OA
Fabrication and electromagnetic wave absorption properties of flake carbonyl iron/polyester fiber reinforced composites
片状羰基铁(flake carbonyl iron powder,CIP)是一种典型的磁性损耗型吸波剂,但是其高密度的特点影响了材料的应用.本研究将其与水性聚氨酯(PU)、涤纶(PET)纤维材料复合,制备并考察了这种纤维吸波复合材料(CIP/PET/PU)的性能.首先,将2种不同尺寸的CIP,分别以不同浓度分散到PU溶液中形成浸渍液;其次,将纤维材料(PET)没入浸渍液中,得到CIP/PET/PU.通过对CIP/PET/PU的微观形貌、吸波性能和力学性能的测试分析,发现在CIP/PET/PU正面和反面的微观形貌存在差异,横截面中CIP呈现从反面密集到正面稀疏的梯度分布特征,且尺寸较大的CIP更容易在材料反面形成致密的结构.CIP/PET/PU反面吸波性能显著优于正面,在采用较大尺寸CIP且m(CIP)∶m(PU)=1.5 时,CIP/PET/PU 在 18 GHz 处达到最低反射损耗-25 dB;即使在 m(CIP)∶m(PU)=0.15 的低填充量下仍存在有效吸收.CIP/PET/PU与未添加CIP的复合材料力学性能相比,呈现出不同的变化规律:当CIP尺寸较小且m(CIP)∶m(PU)=0.015时,CIP/PET/PU的力学性能比未添加CIP的略高或者接近;而当CIP尺寸较大且m(CIP)∶m(PU)=1.5时,CIP/PET/PU的力学性能略优于未添加CIP的复合材料,而其他样品都显示出较差的力学性能.
Flake carbonyl iron powder(CIP)is a typical magnetic-loss electromagnetic wave absorber,but its high density limits practical application.In this study,CIP was compounded with waterborne polyurethane(PU)and polyester fiber(PET)to prepare CIP/PET/PU composites,and their performance was systematically investigated.Two CIP sizes were each dispersed at different mass ratios into PU solutions to form impregnation solutions,into which PET fibers were subsequently immersed to yield CIP/PET/PU.Characterization of the microstructure,microwave ab-sorption properties,and mechanical performance revealed distinct differences between the front and back sides of the composite.The cross-section exhibited a gradient distribution of CIP,transitioning from a dense concentration at the back side to a sparse distribution at the front side,with larger CIP particles being more prone to forming a dense struc-ture on the back side.The microwave absorption performance of the back side was significantly superior to that of the front side.For composites containing larger CIP at a mass ratio of m(CIP)∶m(PU)=1.5,the minimum reflection loss reached-25 dB at 18 GHz.Effective absorption was still achieved at a low mass ratio of m(CIP)∶m(PU)=0.15,indi-cating promising potential for lightweight composites.Regarding mechanical properties,composites with smaller CIP at m(CIP)∶m(PU)=0.015 showed mechanical performance slightly higher than or comparable to that of the CIP-free composite.Similarly,composites with larger CIP at m(CIP)∶m(PU)=1.5 exhibited slightly better mechanical properties than the CIP-free composite.However,all other samples showed inferior mechanical performance compared with the CIP-free composite.
金欣怡;郭楠楠;冯进刚;何恒鑫;朱立成;庞添文;顾闻彦
南通大学纺织服装学院,江苏南通 226019南通大学纺织服装学院,江苏南通 226019南通大学纺织服装学院,江苏南通 226019南通大学纺织服装学院,江苏南通 226019武汉纺织大学先进纺纱织造及清洁生产国家地方联合工程实验室,湖北武汉 430200南通大学纺织服装学院,江苏南通 226019南通大学纺织服装学院,江苏南通 226019||南通大学安全防护用特种纤维复合材料研发国家地方联合工程研究中心,江苏南通 226019
轻工纺织
羰基铁聚氨酯聚酯纤维吸波反射损耗力学性能
carbonyl ironpolyurethanepolyester fiberelectromagnetic wave absorptionreflection lossmechanical properties
《南通大学学报(自然科学版)》 2026 (1)
40-47,8
先进纺纱织造及清洁生产国家地方联合工程实验室2024年开放基金项目(FX20240012)
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