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氧化对闪锌矿可浮性的影响及机理OA

Effect of Oxidation on Floatability of Sphalerite and its Mechanism

中文摘要英文摘要

[目的]为研究闪锌矿氧化及氧化后对可浮性的影响,[方法]将闪锌矿分别置于空气、水、高锰酸钾及过氧化氢水溶液等介质中进行氧化,在适宜的pH值下,利用3种捕收剂DJHY、BXZX、JXZZ对经过不同条件氧化后的闪锌矿进行浮选,并通过红外光谱分析、接触角检测和Zeta电位检测等手段探究了氧化对闪锌矿可浮性的影响.[结果与结论]氧化实验结果表明,闪锌矿经不同条件氧化的氧化程度不同;接触角检测、浮选实验结果表明,闪锌矿经轻度氧化后可浮性提高,经过度氧化后可浮性降低;红外光谱检测表明,3种捕收剂DJHY、BXZX、JXZZ与闪锌矿之间的作用方式均存在化学吸附;Zeta电位检测表明,闪锌矿水中氧化后捕收剂对其电动电位影响大于在空气中氧化.

[Objective]In order to clarify,the oxidation of sphalerite and its influence on floatability,[Method]the sphalerite was oxidized in air,water,potassium permanganate and aqueous hydrogen peroxide solution,respectively.At a suitable pH value,the sphalerite oxidized at different conditions was floated by three collectors,DJHY,BXZX and JXZZ.The influence of oxidation on the floatability of sphalerite was explored by means of infrared spectrum analysis,contact angle detection and Zeta potential detection.[Result & Conclusion]Oxidation test shows that the oxidation degree of sphalerite is different at different conditions.The results of contact angle detection and flotation test show that the floatability of sphalerite is improved after mild oxidation,but decreased after moderate oxidation.Infrared spectrum detection shows that there is chemical adsorption between the three collectors DJHY,BXZX and JXZZ and sphalerite.Zeta potential detection shows that the collector has greater influence on the electrokinetic potential of sphalerite after oxidation in water than in air.

刘子源;代淑娟;李鹏程;陈瑜;董丽鑫

辽宁科技大学矿业工程学院,辽宁 鞍山 114051辽宁科技大学矿业工程学院,辽宁 鞍山 114051辽宁科技大学矿业工程学院,辽宁 鞍山 114051辽宁科技大学矿业工程学院,辽宁 鞍山 114051辽宁科技大学矿业工程学院,辽宁 鞍山 114051

矿业与冶金

闪锌矿氧化浮选促进Zeta电位

sphaleriteoxidationflotationpromoteZeta potential

《矿产综合利用》 2026 (2)

21-28,8

国家自然科学基金(No.52174254)

10.12476/kczhly.202307310421

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