地下爆破作业产生的CO有害气体的色敏监测与催化抑制OA
Research on Carbon Monoxide Coordinated Control Technology for Underground Blasting Operations-Integrated Application of Catalytic Suppression and Colorimetric-Sensitive Monitoring
地下爆破作为矿山开采与隧道施工的核心工序,其产生的一氧化碳(CO)等有害气体对作业安全构成严重威胁.由于地下空间封闭性强、通风条件受限,传统通风法及水封法在CO浓度控制方面存在显著不足,同时传统气体传感器响应滞后性与采样预处理需求难以匹配爆破场毫秒级动态释放特性.针对地下爆破作业一氧化碳(CO)动态释放控制与实时监测的技术难题,本研究提出"催化抑制-色敏监测"协同控制体系.通过水热合成法制备分级孔结构Co3O4 催化剂,结合氧平衡理论优化模型,实现炸药爆炸CO生成量降低 58.23%.研究表明:当Co3O4 添加量为炸药质量的 5%时,作业面CO浓度显著下降;0.6%Pd负载量的Pd/TiO2 材料对CO的监测效果最佳.研究为地下工程构建"生成抑制-动态监测-智能调控"三位一体安全体系提供了创新解决方案.
Underground blasting,as a core process in mining and tunnel construction,generates hazardous gases such as carbon monoxide(CO),which pose a serious threat to operational safety.Due to the strong enclosure of underground space and limited ventilation conditions,traditional ventilation methods and water-sealing methods are inadequate for controlling CO concentrations.Moreover,the delayed response and the need for sample pretreatment of conventional gas sensors cannot meet the millisecond-scale dynamic release characteristics of blasting field.To address the technical challenges of controlling and monitoring the dynamic release of CO during underground blasting,this study proposes an integrated ″catalytic suppression-colorimetric monitoring″ system.A hierarchically porous Co3O4 catalyst was prepared via hydrothermal synthesis,and its formulation was optimized based on oxygen balance theory,achieving a 58.23%reduction in CO generation from explosives.The results indicate that adding Co3O4 at 5%of the explosive mass significantly lowers the CO concentration at the working face,while Pd/TiO2 with 0.6%Pd loading exhibits the best performance for CO monitoring.This study provides an innovative solution for establishing a trinity safety system of ″generation suppression-dynamic monitoring-intelligent regulation″in underground engineering.
刘玉蓉;赵智超;刘旭文;李经纬
江汉大学 精细爆破全国重点实验室,爆破工程湖北省重点实验室,湖北 武汉 430056江汉大学 精细爆破全国重点实验室,爆破工程湖北省重点实验室,湖北 武汉 430056江汉大学 精细爆破全国重点实验室,爆破工程湖北省重点实验室,湖北 武汉 430056江汉大学 精细爆破全国重点实验室,爆破工程湖北省重点实验室,湖北 武汉 430056
矿业与冶金
地下爆破一氧化碳抑制Co3O4催化剂色敏传感氧平衡理论
underground blastingcarbon monoxide suppressionCo3O4 catalystcolorimetric sensingoxygen balance theory
《江汉大学学报(自然科学版)》 2026 (2)
5-17,13
湖北省教育厅科学研究计划青年人才项目(Q20234414)
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