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粒径对Al-Li-Mg合金点火燃烧性能的影响OA

Effect of Particle Size on the Ignition and Combustion Performance of Al-Li-Mg Alloys

中文摘要英文摘要

为探究Al-Li-Mg合金粒径对其点火燃烧行能的影响机制,以中位粒径9、13、16、24 μm的Al-Li-Mg合金为对象,采用激光粒度仪、扫描电镜、X射线衍射仪、同步热分析仪、氧弹量热仪,以及结合高速摄影与光纤光谱仪的激光点火实验台,对其物化性质及点火燃烧行为进行了研究.结果表明:随着Al-Li-Mg合金粒径的增大,点火延迟时间先锐减后趋于平稳,由135 ms降至51 ms,再进一步降至15 ms和18 ms,燃烧强度从7300.4降至1721.6,燃烧时间先略有延长后基本稳定,由857 ms到928 ms至920 ms左右.对比发现,13 μm的Al-Li-Mg合金在点火延迟(51 ms)、持续燃烧时间(928 ms)与燃烧强度(6041.8)之间取得平衡,研究揭示了粒径通过调控热传导效率与元素扩散的竞争机制,以影响Al-Li-Mg合金反应的路径:粒径增大导致热传导受限,促进Li、Mg向表面迁移富集,形成温度梯度并诱发"微爆"效应,缩短点火延迟,降低了燃烧效率与燃烧强度.

To investigate the influence mechanism of particle size of Al-Li-Mg alloy on its ignition and combustion behavior,Al-Li-Mg alloys with median particle sizes of 9,13,16,and 24 μm was selected and tested by using of the laser particle size an-alyzer,scanning electron microscopy,X-ray diffractometry,simultaneous thermal analyzer,oxygen bomb calorimeter,and a la-ser ignition experimental setup combined with high-speed photography and fiber optic spectrometry.Results show that with the increase in particle size of the Al-Li-Mg alloy,the ignition delay time sharply decreases and then stabilizes,dropping from 135 ms to 51 ms,and further to 15 ms and 18 ms.The combustion intensity decreases from 7300.4 to 1721.6,while the com-bustion duration slightly prolongs and then remains largely stable from 857 ms to 928 ms,until to approximately 920 ms.A com-prehensive comparison indicates that the Al-Li-Mg alloy with a particle size of 13 μm achieves a balance among ignition delay(51 ms),combustion duration(928 ms),and combustion intensity(6041.8).The study reveals that particle size affects the re-action pathway of the Al-Li-Mg alloy by regulating the competitive mechanism between heat conduction efficiency and elemen-tal diffusion.An increase in particle size limits heat conduction and promotes the migration and enrichment of Li and Mg toward the surface,which forms a temperature gradient and induces a"micro-explosion"effect,shortens the ignition delay,but reduces combustion completeness and combustion intensity.

曾绮卉;王鼎程;陈玉坤;常亚蒙;李春涛;蒲旸;罗鹏凯;李伟;王芳

航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003

军事科技

金属燃料Al-Li-Mg合金激光点火粒径

metal fuelAl-Li-Mg alloylaser ignitionparticle size

《含能材料》 2026 (4)

425-434,10

国家自然科学基金(U25B20101,62433017)

10.11943/CJEM2026021

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