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基于微纳结构的AP包覆复合铝粉的性能OA

Energy Release Mechanism of AP-coated Micro/Nano-structured Aluminum Powder

中文摘要英文摘要

为提升铝粉燃料的反应活性与能量释放效率,采用微纳米复合-液相沉积-喷雾干燥法制备高氯酸铵(AP)包覆微纳米复合铝粉,并结合扫描电子显微镜、燃烧热测试、哈特曼管火焰传播及高速红外摄影等方法,系统研究AP包覆微纳结构对粉体燃烧性能的影响规律.结果表明,未包覆体系中,当纳米铝含量为18%时颗粒表面纳米铝粉复合均匀性最佳,燃烧热达到31.3 MJ·kg-1.AP包覆后体系在较高纳米铝含量条件下反应活性仍得到有效保持,其中24%纳米铝样品燃烧热为27.5 MJ·kg-1.AP包覆显著提高火焰传播速度并提前峰值出现时间,18%纳米铝样品最大火焰传播速度由62.81 m·s-1增至67.50 m·s-1.红外摄影结果表明,AP包覆降低火焰峰值温度,高温区由边缘强化向中心集聚转变.

To enhance the reactivity and energy release efficiency of aluminum powder fuel,ammonium perchlorate(AP)-coat-ed micro/nano composite aluminum powder was prepared via a liquid-phase deposition-spray drying method.Scanning electron microscopy(SEM),calorific value measurements,Hartmann tube flame propagation tests,and high-speed infrared imaging were employed to systematically investigate the effects of the AP-coated micro/nano structure on combustion performance.The results indicate that,in the uncoated system,the sample with 18%nano-aluminum exhibited the most uniform particle surface distribution,achieving a calorific value of 31.3 MJ·kg-1.In the AP-coated system,high reactivity was maintained even at elevat-ed nano-aluminum contents,with the 24%nano-aluminum sample exhibiting a calorific value of 27.5 MJ·kg-1.AP coating signif-icantly increased the flame propagation velocity and advanced the peak occurrence time;for the 18%nano-aluminum sample,the maximum flame propagation velocity increased from 62.81 to 67.50 m·s-1.Infrared imaging results indicate that AP coating reduces the peak flame temperature and shifts the high-temperature zone from edge-enhanced to centrally concentrated.

夏语;罗一民;程志鹏;张传彪;刘大斌;徐森

南京理工大学 化学与化工学院,江苏 南京 210094江苏智仁景行新材料研究院有限公司,江苏 南京 210014南京理工大学 化学与化工学院,江苏 南京 210094南京理工大学 化学与化工学院,江苏 南京 210094南京理工大学 化学与化工学院,江苏 南京 210094南京理工大学 化学与化工学院,江苏 南京 210094||国家民用爆破器材质量监督检测中心,江苏 南京 210094

军事科技

燃烧复合铝粉AP包覆

combustionAl composite powderAP-coated

《含能材料》 2026 (4)

389-398,10

国家自然科学基金(12272184)National Natural Science Foundation of China(No.12272184)

10.11943/CJEM2026075

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