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RGO/CBNNTs复合材料的设计及微波吸收性能OA

Preparation and microwave absorption properties of RGO/CBNNTs composite

中文摘要英文摘要

以氧化石墨烯(GO)作为基底材料,MgCl2 为催化剂,在 N2 与 NH3 的混合气氛下,利用化学气相沉积法将GO转化成还原氧化石墨烯(RGO),同时在其表面生长崩溃型氮化硼纳米管(CBNNTs)合成 RGO/CBNNTs复合材料.通过控制反应温度(800、850、900℃)可有效地抑制副产物 MgF2 的生成并控制 CBNNTs管壁内径的生长,进而制备出三种 RGO/CBNNTs复合材料.通过对 RGO表面负载不同管径的 CBNNTs,考察 RGO/CBNNTs复合材料在 2~18 GHz频段内的吸波性能.其中 RGO/CBNNTs-900的吸波性能最佳,根据测试数据可知,在 13.36 GHz处 RGO/CBNNTs-900的最小反射损耗(RLmin)达到-49.17 dB,匹配厚度仅为 1.59 mm,上述各项参数均强于RGO.由于 RGO的电导率较高且介电常数较大,极其容易引起电磁阻抗失配问题.而 CBNNTs的引入将RGO的 ε'从 7.7降低到 5.1,缓解 RGO电导率较高、介电常数较大的问题,提升微波吸收性能,此方法为 RGO 材料在微波吸收领域的应用提供新的思路.

Graphene oxide(GO)is used as the substrate material and MgCl2 is used as the catalyst.Under a mixed atmosphere of N2 and NH3,GO is converted into reduced graphene oxide(RGO)by chemical vapor deposition.Meanwhile,collapse boron nitride nanotubes(CBNNTs)are grown on its surface to synthesize RGO/CBNNTs composite materials.By controlling the reaction temperature(800,850,900℃),the generation of by-product MgF2 can be effectively inhibited and the growth of the inner diameter of CBNNTs tube wall can be controlled,thereby preparing three types of RGO/CBNNTs composite materials.The wave absorption performance of RGO/CBNNTs composite in the 2-18 GHz frequency band is investigated by attaching CBNNTs of different pipe diameters to the surface of RGO.Among them,the absorption performance of RGO/CBNTS-900 is the best.According to the test data,at 13.36 GHz,the minimum reflection loss(RLmin)of RGO/CBNTS-900 reaches-49.17 dB,and the matching thickness is only 1.59 mm.All the above parameters are stronger than those of RGO.Due to the high electrical conductivity and large dielectric constant of RGO,it is extremely prone to causing electromagnetic impedance mismatch problems.The introduction of CBNNTs has reduced the ε'of RGO from 7.7 to 5.1,alleviating the problems of high electrical conductivity and large dielectric constant of RGO,and improving the microwave absorption performance.This method provides a new idea for the application of RGO materials in the field of microwave absorption.

胡琦;徐晨皓;齐存康;华玉龙;张静;王月敏

天津中德应用技术大学 航空航天学院,天津 300350天津中德应用技术大学 航空航天学院,天津 300350天津中德应用技术大学 航空航天学院,天津 300350天津中德应用技术大学 航空航天学院,天津 300350天津中德应用技术大学 航空航天学院,天津 300350天津中德应用技术大学 航空航天学院,天津 300350

通用工业技术

还原氧化石墨烯崩溃型氮化硼纳米管化学气相沉积法微波吸收性能

reduced graphene oxidecollapsed boron nitride nanotubechemical vapor depositionmicrowave absorption perform-ance

《航空材料学报》 2026 (4)

52-63,12

天津市教委高等教育科技发展基金(2023KJ244)

10.11868/j.issn.1005-5053.2025.000142

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