SiC遮光剂对SiO2气凝胶复合材料热导率的影响OA
Effect of SiC opacifier on thermal conductivity of SiO2 aerogel composite material
高温下SiO2气凝胶热导率大幅增加,添加遮光剂可以显著提升其隔热性能.采用有限元分析法(finite element method,FEM),建立了SiC遮光剂掺杂SiO2气凝胶复合材料周期性体积单元模型,对其施加周期性边界条件,分析了SiC遮光剂粒径和掺杂量对SiO2气凝胶材料气固耦合热导率的影响,结合Mie理论辐射热导率值,分析了掺杂SiC遮光剂有效热导率的变化规律.结果表明,气固耦合热导率随SiC体积分数增加而增加,辐射热导率随体积分数增加而减小,确定了不同温度和体积分数下辐射热导率最低值对应的最优粒径,得出了不同温度下使复合材料有效热导率降至最低的遮光剂参数.
The thermal conductivity of SiO2 aerogel increases significantly at high temperatures,and the addition of occlusive agents can significantly improve its thermal insulation performance.A periodic volume element model of SiC occlusive agent-doped SiO2 aerogel composites was established using the finite element method(FEM).Periodic boundary conditions were applied to the model,and the effects of SiC occlusive agent particle size and doping amount on the gas-solid coupling thermal conductivity of SiO2 aerogel materials were analyzed.By combining with radiative thermal conductivity calculated via Mie theory,variation law of effective thermal conductivity of SiC doped SiO2 aerogel composites was investigated.The results show that gas-solid coupled thermal conductivity increases with an increase in the volume fraction of SiC opacifier,resulting into a decrease in the radiative thermal conductivity.A connection of particle size to minimum radiative thermal conductivity has been determined for the SiO2 aerogel composites,with varies of temperatures and volume fractions.And a connection of opacifier parameter to minimum thermal conductivity was also identified.
殷金英;乔鑫垚;宋书宇
哈尔滨理工大学测控技术与通信工程学院,黑龙江 哈尔滨 150080哈尔滨理工大学测控技术与通信工程学院,黑龙江 哈尔滨 150080哈尔滨理工大学测控技术与通信工程学院,黑龙江 哈尔滨 150080
能源科技
气凝胶周期性边界条件气固耦合热导率辐射热导率数值模拟
aerogelperiodic boundary conditionsgas-solid coupled thermal conductivityradiative thermal conductivitynumerical simulation
《化工学报》 2026 (3)
1587-1596,10
哈尔滨工业大学特种环境复合材料技术国家级科技重点实验室基金项目(6142905192514)
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