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X65MS埋弧焊管SSC环境下腐蚀沟槽产生原因分析OA

Reason Analysis for SSC Corrosion Groove of X65MS Submerged Arc Welded Pipe

中文摘要英文摘要

硫化氢腐蚀是造成油气管材失效的主要原因之一,对某X65MS钢级埋弧焊管进行硫化氢应力腐蚀试验(SSC),发现母材、热影响区、焊缝区拉伸表面都存在大量的腐蚀沟槽,所有的腐蚀沟槽垂直于拉应力方向.通过对材料进行理化性能、显微组织、硬度和表面残余应力测试,分析了SSC腐蚀特征及SSC试样产生腐蚀沟槽的原因.结果表明,材料的理化性能满足标准要求,但表层的显微组织存在M-A硬相组织,且硬度分布不均,局部超过标准规定的250HV0.3;试验材料进行热处理后,表面硬度得到改善,硬度最高为226HV0.3,表面最大残余应力从295 MPa降低到123 MPa;重新取样进行SSC复检,未出现腐蚀沟槽,说明表面硬度和残余应力对SSC试验产生腐蚀沟槽有显著影响,通过降低硬度和控制残余应力能有效降低和改善X65MS的抗SSC性能.

Hydrogen sulfide corrosion is the main cause of the oil and gas pipe failure.Hydrogen sulfide stress corrosion test(SSC)is conducted on a X65MS steel grade submerged arc welded pipe.It is found that numerous corrosion grooves appear on the tensile surfaces of all base materials HAZ and weld zones,all of which were perpendicular to the direction of tensile stress.By conducting tests on the physical and chemical properties,microstructure,hardness,and surface residual stress of the material,the corrosion characteristics of SSC were analysed and the reasons for the appearance of corrosion grooves in SSC samples were explored.Results show that the physical and chemical properties of the material meet the standard requirements,but there is a hard phase(M-A island structure)in the microstructure of the surface layer,and the hardness distribution is uneven,exceeding the standard specified 250HV0.3.After heat treatment of the material,the surface hardness was improved,with a maximum hardness of 226HV0.3.The residual stress on the surface decreased from 295 MPa to 123 MPa.Sampling was conducted for SSC retesting,and no corrosion grooves were found.The surface hardness and residual stress had a significant impact on the occurrence of corrosion grooves in the SSC test.By reducing hardness and controlling residual stress,the SSC performance of X65MS can be effectively improved.

张德平;李明卓;王大成;张钊;刘雨桐

中国石油吉林油田分公司,吉林 松原 138000中国石油吉林油田分公司,吉林 松原 138000中国石油吉林油田分公司,吉林 松原 138000中国石油吉林油田分公司,吉林 松原 138000中国石油吉林油田分公司,吉林 松原 138000

矿业与冶金

X65MS埋弧焊管硫化氢应力腐蚀腐蚀沟槽残余应力表面硬度

X65MS SAWLSSCcorrosion grooveresidual stresssurface hardness

《焊管》 2026 (4)

58-63,69,7

新型油气勘探开发国家科技重大专项"CO2 驱大幅度提高采收率与长期封存技术"(项目编号2024ZD1406600)中国石油科技项目"CCUS注采工艺、产出气循环利用及高效防腐关键技术研究"(项目编号2021ZZ01-04).

10.19291/j.cnki.1001-3938.2026.04.008

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