基于LAP增强剂的高强度HTPB推进剂力学性能研究OA
Mechanical properties of high-strength HTPB propellants enhanced by LAP agents
固体推进剂力学性能对固体火箭发动机结构完整性和工作可靠性具有重要意义.针对端羟基聚丁二烯(HTPB)高强度复合推进剂最大伸长率易下降的共性问题,在 HTPB 推进剂体系中引入二醇类扩链剂 LAP 作为增强剂,系统研究了增强剂含量、固化参数及键合剂用量对 HTPB 推进剂单轴拉伸力学性能的影响,并揭示其高低温力学性能变化规律.同时,结合小角 X 射线散射(SAXS)研究了黏合剂基体的微相分离结构.结果表明,LAP 的引入使得黏合剂基体的SAXS 散射峰由约 11.7 nm 移动至 6.6 nm 且峰型更清晰,表明微相分离结构得到强化;该结构作为物理交联点增强了基体的力学性能,使得 HTPB 推进剂的抗拉强度显著提高,在 20℃下可达到 3.36 MPa,最大伸长率仍保持在 27%.
The mechanical properties of solid propellants are of great significance to the structural integrity and operational reliability of solid rocket motors.To tackle the typical issue of reduced maximum elongation in high-strength HTPB composite propellants,a diol-type chain extender LAP was introduced as a reinforcing agent.The effects of reinforcing agent content,curing parameters,and bonding agent on the uniaxial tensile properties of the propellants were systematically investigated,and their mechanical behavior under different temperatures was also analyzed.Meanwhile,small-angle X-ray scattering(SAXS)was used to characterize the microphase-separated structure of the binder matrix.The results show that the introduction of LAP shifts the SAXS scattering peak of the binder matrix from approximately 11.7 nm to 6.6 nm,with a clearer peak profile,indicating an enhanced microphase-separated structure.This structure serves as physical cross-linking points,which significantly improve the tensile strength of the propellant,reaching 3.36 MPa at 20℃,while the elongation at break remains at 27%.
陈旭;姜丽萍;肖啸;杨巍璐;李洋;黄海涛
西安近代化学研究所,西安 710065西安近代化学研究所,西安 710065西安近代化学研究所,西安 710065西安近代化学研究所,西安 710065西安近代化学研究所,西安 710065西安近代化学研究所,西安 710065
航空航天
高强度HTPB推进剂力学性能LAP增强剂小角X射线散射微相分离
High-strength HTPB propellantsmechanical propertyLAP reinforcing agentsmall-angle X-ray scatteringmicrophase-separation
《固体火箭技术》 2026 (2)
260-266,7
评论