基于KH570-PS表面修饰纳米Al2O3环氧树脂复合材料的性能分析OA
Performance Analysis of Epoxy Resin Composite Material with Surface-Modified Nano-Al2O3 Based on KH570-PS
为改善电力系统中环氧树脂复合材料在湿热环境中的综合性能,本研究使用硅烷偶联剂(KH570)对纳米Al2O3进行接枝改性,并用苯乙烯(PS)接枝处理增强了纳米Al2O3在环氧树脂中的相容性,分别制作纳米Al2O3含量分别为1%、3%和5%的改性环氧树脂样品,从测试样品的微观形貌,表面凝露质量,静态接触角、吸水率、表面/体积电阻率等方面,探究了不同质量分数的改性纳米Al2O3对环氧树脂性能的影响.结果表明:经KH570-PS接枝改性后的纳米Al2O3粒子,可以均匀分散于环氧树脂中,环氧树脂表面无明显团聚现象;改性后的环氧树脂会显著降低表面的凝露质量;随着Al2O3浓度提升,接枝改性后样品吸水率会下降,同时憎水性会得到增强;接枝改性后可以缓解纳米Al2O3带来体积电阻率下降的现象,并且显著提高环氧树脂的表面电阻率.本研究的研究成果对提升环氧树脂绝缘材料在湿热环境中运行性能提供参考,具有一定的工程实用价值.
In order to improve the comprehensive performance of epoxy resin composite materials in power system,the author used silane coupling agent(KH570)to graft nano-Al2O3,and used styrene(PS)to enhance the compatibility of nano-Al2O3 in epoxy resin.Modified epoxy resin samples with Al2O3 con-tent of 1%,3%and 5%were prepared,respectively.The effects of modified nano-Al2O3 with different mass fractions on the properties of epoxy resin were investigated from the aspects of micro-morphology,surface condensation quality,static contact angle,water absorption and surface/volume resistivity of the samples.The results show that the nano-Al2O3 particles modified by KH570-PS graft can be uniformly dispersed in the epoxy resin,and there is no obvious agglomeration on the surface of the epoxy resin.The modified epoxy resin can significantly reduce the condensation quality of the surface.With the increase of Al2O3 concentration,the water absorption of grafted samples decreased and the hydrophobicity was en-hanced.After graft modification,the decrease of volume resistivity caused by nano-Al2O3 can be allevi-ated,and the surface resistivity of epoxy resin can be significantly improved.The research results provide reference for improving the performance of epoxy resin insulation materials in hot and humid environment,and have certain engineering practical value.
杨占刚;籍勇亮;王晓峰;付彬;佟忠赫;毕茂强
国网重庆市电力公司市北供电分公司,重庆 401147国网重庆市电力公司,重庆 400014国网重庆市电力公司市北供电分公司,重庆 401147国网重庆市电力公司市北供电分公司,重庆 401147重庆理工大学电气与电子工程学院,重庆 400054重庆理工大学电气与电子工程学院,重庆 400054
接枝改性环氧树脂纳米氧化铝憎水性电阻率
graft modificationepoxy resinnano-aluminahydrophobicresistivity
《电瓷避雷器》 2026 (2)
74-82,9
国家自然科学基金项目(编号:51607019)国网重庆市电力公司科技项目(编号:2023渝电科技50#).Project supported by National Natural Science Foundation of China(No.51607019)State Grid Chongqing Electric Power Company Technology Project(No.2023 Yudian Technology 50#).
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