首页|期刊导航|电瓷避雷器|Y/Ce共掺杂对高梯度压敏陶瓷电阻综合电性能的改善

Y/Ce共掺杂对高梯度压敏陶瓷电阻综合电性能的改善OA

Improvement of Comprehensive Electrical Properties of High Gradient Varistors by Y/Ce Co-Doping

中文摘要英文摘要

对ZnO基压敏电阻进行了Y、Ce两种元素的共掺杂,通过改变Y和Ce之间的比例,寻找最优的Y、Ce共掺杂比例.通过X射线衍射仪、扫描电镜对样品的微观结构进行表征,利用对数正态分布概率密度函数对晶粒粒径分布进行了拟合.利用金属氧化物直流参数测试仪对样品的压敏电压、漏电流和非线性系数进行测量,利用脉冲电流测试设备测试样品的8/20 µs雷电波残压比与2ms方波电流通流能力.采用精密阻抗分析仪测试样品的C-V特性曲线.研究发现当Y、Ce两种元素协同作用时,能使ZnO晶粒尺寸分布最优化.当两种稀土离子的比例合适时,更易向晶粒内部渗透,富集在晶界处的量更少,晶界势垒更高.压敏电阻结构越均匀,能量的分布越均匀,能承受的能量越大.

The optimal Y and Ce co-doping ratio was determined by adjusting the ratio between Y and Ce.The microstructure of the sample was characterized by X-ray diffraction and scanning electron mi-croscopy,and the grain size distribution was fitted using a lognormal probability density function.Meas-ure the breakdown voltage,leakage current,and nonlinear coefficient of the sample using a metal oxide DC parameter tester,and the 8/20 μs lightning wave pulse and 2 ms square wave pulse current withstand capabilities were tested by a pulse current testing device.The precision impedance analyzer was adopted to test the C-V characteristic curves of the samples.It was found that the coordination of Y and Ce ele-ments can optimize the grain size distribution of ZnO.When the ratio of the two rare earth ions is appro-priate,it is easier to penetrate into the interior of the crystal grain,with less concentration at the grain boundaries,resulting in higher barrier potential.The more uniform the structure of the varistor,the more uniform the energy distribution,and the greater the pulse energy it can withstand.

董建洪

嘉兴瑞嘉电气股份有限公司,浙江嘉兴 314001

共掺杂稀土氧化物压敏电阻电性能高电位梯度

co-dopingrare earth oxidevaristorselectrical performancehigh potential gradient

《电瓷避雷器》 2026 (2)

22-28,7

10.16188/j.isa.1003-8337.2026.02.004

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