基于石墨烯/聚合物自组装悬浮膜气压传感器的制备与性能探究OA
Preparation and performance study of graphene/polymer self-assembled suspended membrane-based air pressure sensors
本文设计并制备了一种基于还原氧化石墨烯悬浮膜(reduced Graphene Oxide Suspended Film,rGO-SF)的气压传感器,其中 rGO-SF 基于自组装氧化石墨烯(Graphene Oxide,GO)薄膜从溶液中自发分离,并在经刻蚀膏处理过的 SiO2表面形成的空腔上原位生长制备而成.相较于传统的石墨烯基气压传感器制备工艺,rGO-SF 气压传感器的制备无需借助膜转移工艺,极大地简化了制备流程,为大规模生产提供了有利条件.此外,在 rGO 层间引入改性聚甲基丙烯酸甲酯(Modified Polymethyl Methac-rylate,M-PMMA)后,M-PMMA/rGO 复合薄膜的氧透过率(Oxygen Transmission Rate,OTR)较原始rGO 降低了49.6%(20.0wt%M-PMMA),显著提高了 rGO-SF 气压传感器的稳定性与可靠性.试验表明,rGO-SF 在内外气压差的作用下会导致其电阻发生变化.基于此原理,通过测量电阻变化,即可实现对气压的精确测量.经测试,该传感器能够检测 0~100 kPa 范围内的气压变化,尤其在 30~100 kPa 气压差区间,呈现出良好的线性度(S2 = 0.99)与灵敏度(1.298×10-3 kPa-1).
This paper presents the design and fabrication of a pressure sensor based on reduced graphene oxide suspended film(rGO-SF).The rGO-SF was formed through in-situ growth on pre-etched SiO2 cavities,where self-assembled graphene oxide(GO)films spontaneously separated from solution.Compared with conventional graphene-based pressure sensor fabrication processes,the rGO-SF sensor eliminates membrane transfer steps,significantly simplifying the manufacturing workflow and providing advantages for large-scale production.By introducing modified polymethyl methacrylate(M-PMMA)into the rGO interlayers,the oxygen transmission rate(OTR)of the M-PMMA/rGO composite film was reduced by 49.6%(at 20.0wt%M-PMMA loading),markedly enhancing the stability and reliability of the rGO-SF pressure sensor.Experimental results demonstrate that pressure differences between internal and external environments induce measurable resistance changes in rGO-SF.Leveraging this principle,pre-cise pressure measurement can be achieved by monitoring resistance variations.Testing shows the sensor effectively detects pressure changes in the 0 kPa to 100 kPa range,with excellent linearity(S2 =0.99)and sensitivity(1.298×10-3 kPa-1)particularly in the 30 kPa to 100 kPa differential pressure regime.
王垚;梅启林;丁国民;申正鹏;高琳沁;王鸿
武汉理工大学 材料科学与工程学院,武汉 430070武汉理工大学 材料科学与工程学院,武汉 430070武汉理工大学 材料科学与工程学院,武汉 430070武汉理工大学 材料科学与工程学院,武汉 430070武汉理工大学 材料科学与工程学院,武汉 430070武汉理工大学 材料科学与工程学院,武汉 430070
通用工业技术
气压传感器还原氧化石墨烯悬浮膜自组装复合材料
pressure sensorsreduced graphene oxidesuspended filmsself-assemblycomposites
《复合材料科学与工程》 2026 (3)
145-154,10
湖北省自然科学基金一般面上项目(2022CFB384)国家自然科学基金(52003120)
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