Nanofiller orientation-enhanced electrocaloric effect:A case study of P(VDF-TrFE-CFE)/Ba_(0.67)Sr_(0.33)TiO_(3) compositesOA
The exceptional breakdown field strength of polymers,combined with the large spontaneous polarization exhibited by inorganic ferroelectric materials,has led to continuous advancements in the records for the giant electrocaloric effect(ECE)in polymer composites enhanced by ferroelectric inorganic components.This study aims to investigate the ECE properties of P(VDF-TrFE-CFE)/Ba_(0.67)Sr_(0.33)TiO_(3)(BST67)composites by analyzing the aspect ratio,composition ratio,and orientation of BST67 nanoparticles in conjunction with the P(VDF-TrFE-CFE)matrix.The results of the P-E loop calculations indicate that all three factors related to the BST67 nanoparticles enhance the ferroelectric polarization value of the composite material.This enhancement is attributed to the longer aspect ratio,higher composition ratio,and improved orientation,which enable the BST67 nanoparticles to achieve a greater electric field strength.The calculation of ΔT using the LGD method reveals that these three factors of BST67 can independently increaseΔT,and they exhibit a synergistic effect on the ECE performance of the ferroelectric polymer.Our conclusions provide valuable insights for future research on ECE in polymer/inorganic ferroelectric composites.
Cancan Shao;Xiaoming Shi;Ke Xu;Rongzhen Gao;Shiyu Tang;Zhaobo Liu;Houbing Huang
Beijing Institute of Technology,Zhuhai Beijing Institute of Technology,Zhuhai,519088,Guangdong,China School of Materials Science and Engineering,Beijing Institute of Technology,Beijing,100081,China Advanced Research Institute of Multidisciplinary Science,Beijing Institute of Technology,Beijing,100081,ChinaSchool of Mathematics and Physics,Institute of Electro Ceramics&Devices,University of Science and Technology Beijing,Beijing,100083,ChinaBeijing Institute of Technology,Zhuhai Beijing Institute of Technology,Zhuhai,519088,Guangdong,China School of Materials Science and Engineering,Beijing Institute of Technology,Beijing,100081,China Advanced Research Institute of Multidisciplinary Science,Beijing Institute of Technology,Beijing,100081,ChinaBeijing Institute of Technology,Zhuhai Beijing Institute of Technology,Zhuhai,519088,Guangdong,China State Key Laboratory of New Ceramics and Fine Processing,School of Materials Science and Engineering,Tsinghua University,Beijing,100084,ChinaBeijing Institute of Technology,Zhuhai Beijing Institute of Technology,Zhuhai,519088,Guangdong,China School of Materials Science and Engineering,Beijing Institute of Technology,Beijing,100081,China Advanced Research Institute of Multidisciplinary Science,Beijing Institute of Technology,Beijing,100081,ChinaBeijing Institute of Technology,Zhuhai Beijing Institute of Technology,Zhuhai,519088,Guangdong,China School of Materials Science and Engineering,Beijing Institute of Technology,Beijing,100081,China Advanced Research Institute of Multidisciplinary Science,Beijing Institute of Technology,Beijing,100081,ChinaBeijing Institute of Technology,Zhuhai Beijing Institute of Technology,Zhuhai,519088,Guangdong,China School of Materials Science and Engineering,Beijing Institute of Technology,Beijing,100081,China Advanced Research Institute of Multidisciplinary Science,Beijing Institute of Technology,Beijing,100081,China
通用工业技术
P(VDF-TrFE-CFE)/Ba_(0.67)Sr_(0.33)TiO_(3)nanofillers compositesElectrocaloric effectAspect ratioGrain orientationOrientation enhancement effect
《Journal of Materiomics》 2026 (1)
P.112-120,9
supported by the National Natural Science Foundation of China(Grant No.92463306 and No.52372100).
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