油基钻井液用多元类结构环保乳化剂OA
Research on Class Structural Environmentally Friendly Emulsifiers for Oil-based Drilling Fluids
采用含有环保脂酯类衍生物环氧脂肪酸酯为原材料与多胺反应形成具有双子表面活性剂结构的主乳化剂,再以主乳化剂为原材料,通过部分磺化形成具有类似结构的油基钻井液用多元类结构环保乳化剂.通过红外与质谱表征确定了乳化剂分子结构,抗温能够达到 180℃,破乳电压达到 900 V以上,乳化率超过 90%.能够适应低油水比油基钻井液环境,适应不同基础油配制的不同密度钻井液体系.具有优异的生物可降解能力.建立了一种乳滴微观形貌的评价方法来判断乳化剂形成乳滴的稳定性,确定了乳化剂加量高的条件下可以改善油包水乳滴的均匀性与高温稳定性.
Using environmentally friendly ester derivatives such as epoxy fatty acid esters as raw materials,react with polyamines to form a main emulsifier with a Gemini surfactant structure.Then,using the main emulsifier as raw material,partially sulfonate it to form a multi class environmentally friendly emulsifier with a similar structure for oil-based drilling fluids.The molecular structure of the emulsifier was determined through infrared and mass spectrometry characterization,with a temperature resistance of up to 180℃,a demulsification voltage of over 900 V,and an emulsification rate of over 90%.Capable of adapting to low oil-water ratio oil-based drilling fluid environments and drilling fluid systems formulated with different base oils.Adapt to drilling fluid systems with different densities.Has excellent biodegradability.A method for evaluating the microstructure of emulsion droplets was established to determine the stability of emulsion droplet formation,and it was determined that high emulsifier dosage can effectively improve the uniformity and high-temperature stability of oil in water emulsion droplets.
程丙方;王承俊;卜凡康;鲍伶函;王重重;相鹏
中石化胜利石油工程有限公司,山东 东营 257000中石化胜利石油工程有限公司,山东 东营 257000中石化胜利石油工程有限公司,山东 东营 257000中石化胜利石油工程有限公司,山东 东营 257000中石化胜利石油工程有限公司,山东 东营 257000中石化胜利石油工程有限公司,山东 东营 257000
能源科技
油基钻井液乳化剂脂肪酸酯类结构
Oil-based drilling fluidEmulsifierFatty acid estersType structure
《钻井液与完井液》 2026 (2)
188-193,6
中石化集团公司项目"钻井液用合成基础油及体系研究与应用"(P23115).
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