一种新型无固相钻井液抗高温增黏剂OA
A New High-temperature Tackifier for Solid-free Drilling Fluids
辽河油区奥陶系潜山油层中部温度高达 200℃,地层压力系数仅为 1.01~1.06,属于典型的高温低压油气藏.为安全优质钻进与高效保护油气层,亟需研发一种适用于无固相水基钻井液的抗高温增黏剂.通过分子结构优化,以 N-乙烯基吡咯烷酮(NVP)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)、N,N-二乙基丙烯酰胺(DEAA)、1-(3-磺丙基)-2-乙烯基吡啶氢氧化物内盐为主要原料,N,N'-亚甲基双丙烯酰胺(MBA)为交联剂,过硫酸钾和无水亚硫酸氢钠为引发剂,研制出一种抗高温耐盐增黏剂.红外光谱与热重分析表明,其初始分解温度为 296.66℃,降解阶段质量损失仅 45.96%,性能优于国外同类产品 HE300.0.5%浓度水溶液的稠度系数 K可达 722 Pa·sn,增黏效果突出,抗温可达 220℃,抗盐可达饱和.现场应用试验表明,该增黏剂抗高温增黏效果突出,为深层高温潜山油气资源钻探开发提供了钻井液技术支持.
The Ordovician buried-hill reservoir in Liaohe Oilfield exhibits a challenging high-temperature(200℃at reservoir center)and low-pressure(pressure coefficient 1.01~1.06)environment characteristic of typical high-temperature,low-pressure oil/gas reservoirs.To achieve formation protection,a solids-free water based drilling fluid was prioritized,with tackifier selection being critical.Through molecular structure optimization,a novel high-temperature/salt-resistant tackifier was developed using four monomers:N-vinylpyrrolidone(NVP),2-acrylamido-2-methylpropane sulfonic acid(AMPS),N,N-diethylacrylamide(DEAA),and 1-(3-sulfopropyl)-2-vinylpyridinium hydroxide inner salt.The synthesis employed N,N'-methylene bisacrylamide as crosslinker with potassium persulfate and sodium bisulfite as redox initiators.FTIR and TGA analysis confirmed successful polymerization,demonstrating superior thermal stability with 296.66℃initial decomposition temperature and only 45.96%mass loss during degradation phase,outperforming commercial HE300.The fluid achieved remarkable rheological performance with 722 consistency coefficient(K)at 0.5%concentration.Laboratory evaluations verified exceptional thermal stability up to 220℃and saturated salt tolerance.Field applications demonstrated excellent viscosity-enhancing performance and robust durability of this novel tackifier,providing vital technical support for buried-hill reservoir development and high-temperature formation drilling operations.
周国伟;张鑫;阎卫军;华桂友;张振华;邱正松
中国石油集团长城钻探工程有限公司,北京 100020中国石油集团长城钻探工程有限公司,北京 100020中国石油集团长城钻探工程有限公司,北京 100020中国石油集团长城钻探工程有限公司,北京 100020中国石油集团长城钻探工程有限公司,北京 100020中国石油大学(华东)石油工程学院,山东 青岛 266580
能源科技
抗高温耐盐增黏剂无固相钻井液深层潜山
High-temperature resistantSalt-tolerantTackifierSolid-free drilling fluidBuried hill
《钻井液与完井液》 2026 (2)
161-171,11
国家重点研发计划"中国-沙特石油能源"一带一路"联合实验室建设与联合研究"(2022YFE0203400)中国石油长城钻探项目"抗200℃高温水基钻井液体系及核心处理剂新材料研究"(GWDC2024-01-AHX-04).
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